Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing
Reexamination Certificate
2000-05-01
2002-03-26
Vollano, Jean F. (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Sulfur containing
Reexamination Certificate
active
06362374
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention involves a composition containing polysulfides and inhibitors that has a reduced odor level, and a method to reduce the odor level of polysulfides. These polysulfide compositions with a reduced odor level are more useful in various commercial applications such as metalworking fluids.
2. Description of the Related Art
Polysulfides have been found to provide many useful functions in various areas of commerce.
Polysulfides can function as antiwear agents, extreme-pressure agents and antioxidants in lubricants such as gear oils and metalworking fluids. Polysulfides can also function as presulfiding agents for hydrotreating and hydrocracking catalysts used in refinery operations. Polysulfides can also find use as vulcanization agents in the production of elastomers and as metal passivation agents for use in high-temperature furnace operations.
Most of these areas of use require polysulfides that have a high sulfur content and corresponding increase in the higher and less stable polysulfide homologues, starting with tetrasulfides on up, in addition to increased levels of H
2
S (hydrogen sulfide) and unreacted or free sulfur. These high sulfur content polysulfides can generate H
2
S upon storage. The presence of this H
2
S contributes to an obnoxious odor and, above threshold limits, becomes a safety and environmental hazard because H
2
S is toxic and flammable. In addition, H
2
S is an irritant. Consequently, polysulfides having a reduced odor level and methods to reduce the odor level of polysulfides are highly desirable.
Japanese Patent Application 8,245,562, published on Sep. 24, 1996, discloses the use of methyl acrylate as a H
2
S scavenger for the production of an alkyl isothiocyanate from an alkyl dithiocarbamate precursor by treating the carbamate precursor with the acrylate.
U.S. Pat. No. 5,008,432, issued on Apr. 16, 1991, deals with the production of mercaptan-containing compounds by reacting a compound having an activated, olefinic double bond such as methyl acrylate with H
2
S in the presence of a catalyst.
U.S. Pat. No. 4,340,707, issued Jul. 20, 1982, involves oligomers as intermediates to UV-hardenable binders or coatings that are prepared by reacting H
2
S or polyfunctional mercaptans with polyfunctional acrylates.
Using the method of the present invention to reduce the odor level of polysulfides to acceptable levels, based on odor and safety and environmental criteria, gives polysulfide compositions that are readily useful in various applications. The polysulfide compositions of the present invention generally include a non-nitrogen-containing inhibitor that can be advantageous for use as presulfiding agents of refinery catalysts and as metal passivation agents in high-temperature furnace operations.
SUMMARY OF THE INVENTION
The present invention provides a method for reducing the odor level of a polysulfide composition.
The present invention is also directed to a composition having a reduced odor level comprising a polysulfide and an inhibitor selected from the group consisting of hydrocarbyl acrylates and hydrocarbyl methacrylates.
In another embodiment of the present invention, the polysulfide of the composition having a reduced odor level is the reaction product of an olefin selected from the group consisting of isobutylene and diisobutylene with sulfur and H
2
S in the presence of a catalyst.
In a further embodiment of the present invention, a method for reducing the odor level of a polysulfide comprises contacting the polysulfide with an inhibitor selected from the group consisting of hydrocarbyl acrylates and hydrocarbyl methacrylates under conditions that reduce the odor.
In a still further embodiment of the present invention, the polysulfide in the method for reducing the odor level is the reaction product of an olefin selected from the group consisting of isobutylene and diisobutylene with sulfur and H
2
S in the presence of a catalyst.
Additional objects and advantages of the present invention will be set forth in part in the description that follows and in part will be obvious from the description or may be learned by practice of this invention. The objects and advantages of the invention may be realized and attained by means of the instrumentalities pointed out in the appended claims.
DETAILED DESCRIPTION OF THE INVENTION
The composition of the present invention comprises as a first component a polysulfide. The polysulfides of the present invention are sulfur-containing organic compositions that contain one or more sulfur linkages that can be represented by the formula —S— where S is sulfur and x is a number greater than one. These sulfur-containing organic compositions can be acyclic or cyclic. The organic portion of these compositions has a hydrocarbyl makeup; that is, it is predominately hydrocarbon in nature but may have nonhydrocarbon substituent groups and may contain heteroatoms in addition to sulfur.
The polysulfides of the present invention are generally obtained by sulfurizing starting materials using a sulfur source. The starting materials are organic compositions containing one or more olefinic double bonds; that is, double bonds connecting two aliphatic carbon atoms. Examples of organic compositions containing one or more olefinic double bonds are acyclic and cyclic olefins, acyclic polyenes such as 1,4-butadiene and isoprene, cyclic polyenes, unsaturated carboxylic acids and esters, unsaturated fats and oils from plants and animals, and mixtures thereof. Preferred starting materials for the polysulfides of the present invention are isobutylene, diisobutylene and C
8
and higher alpha-olefins and their corresponding structural and geometric isomers including the octenes, the nonenes, the hexadecenes, the octadecenes, the tetracosenes, and the heptacosenes. The sulfur source can be sulfur, sulfur halides such as SCl
2
or S
2
Cl
2
, H
2
S, polysulfide salts, and mixtures thereof. A preferred sulfur source for polysulfides of the present invention is a mixture of sulfur and H
2
S.
The polysulfides of the present invention can be prepared by contacting the starting materials with the sulfur source under conditions that result in the formation of polysulfides. A preferred preparation method for the polysulfides of the present invention involves reacting isobutylene or diisobutylene with sulfur and H
2
S in the presence a catalyst. A preferred catalyst is n-butylamine. Preparation methods for polysulfides of the present invention are presented in U.S. Pat. Nos. 4,119,549 and 4,873,006, the disclosures of which are incorporated herein by reference.
The polysulfides of the present invention can also be prepared by reacting a mercaptan with sulfur in the presence of a basic catalyst as presented in U.S. Pat. No. 5,530,163, the disclosure of which is incorporated herein by reference.
The composition of the present invention comprises, as a second component, an inhibitor selected from the group consisting of hydrocarbyl acrylates and hydrocarbyl methacrylates. The hydrocarbyl group is predominately hydrocarbon in nature but may have nonhydrocarbon substituent groups and may contain heteroatoms such as oxygen. Preferred nonhydrocarbon substituent groups are cyclic ether groups such as epoxy groups represented by the formula
and hydroxy groups. The hydrocarbyl group is preferably a C
2
to C
20
hydrocarbyl group or mixtures thereof. The inhibitors can be monoacrylates, monomethacrylates, polyacrylates or polymethacrylates. Examples of inhibitors of the present invention are 2-ethylhexyl acrylate, 2,6-dimethylheptyl methacrylate, isodecyl methacrylate, n-dodecyl acrylate, C
12-18
acrylate, ethylene glycol dimethacrylate, 1,6-hexanediol diacrylate, trimethylolpropane triacrylate, propoxylated neopentyl glycol diacrylate (available from Sartomer as SR-9003 OLIGOMER®), tetraethylene glycol diacrylate, poly(ethylene glycol) 200 monomethyl ether monomethacrylate, poly(ethylene glycol) 400 monomethyl ether monomethacrylate, glycidyl methacrylate, 2-hydroxyethyl acrylate, and 2-hy
Forester David R.
Gober Victor A.
Malik Bharat B.
Sowerby Roger L.
Fischer Joseph P.
Laferty Sameul B.
Munson Jeffrey F.
The Lubrizol Corporation
Vollano Jean F.
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