Composition for use in organolithium synthesis reactions

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568715, 568821, 568822, 568823, 568834, 568838, 568839, 568846, 568862, 568876, C07C 2700, C07C 2909, C07C 2914

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051498898

ABSTRACT:
A process is disclosed for the preparation of tertiary alcohols, alpha-alkyl substituted nitriles, alkyl-substituted imines or tertiary amines by alkylation of a starting material that is a carbonyl compound or a nitrile followed by hydrolysis wherein the alkylation is carried out with the aid of a reaction system formed by suspending a mixture of:

REFERENCES:
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patent: 4617145 (1986-10-01), Schreiber et al.
patent: 4982017 (1991-01-01), Deberitz et al.
Bartlett et al., "Journal American Chemical," vol. 63: 3229-3230 (1941) QD1.A5.
"J. Amer. Chem. Soc.", vol. 85, pp. 1886-1887 (1963) Lansbury.

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