Metal treatment – Compositions – Fluxing
Reexamination Certificate
2001-02-02
2002-10-22
Wyszomierski, George (Department: 1742)
Metal treatment
Compositions
Fluxing
C148S025000
Reexamination Certificate
active
06468363
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The invention pertains to a flux composition for soldering, for example, a semiconductor chip or a chip carrier module to a printed circuit board.
2. Description of the Related Art
Fluxes play an important role in the procedures used to mount electronic components onto printed circuit cards and printed circuit boards (both of which are hereinafter generically referred to as printed circuit boards or PCBs). For example, one method for directly mounting a semiconductor integrated circuit device (hereinafter called a semiconductor chip or just a chip) onto a PCB is, for example, to form regions of solder, e.g., solder balls, on contact pads on the circuit-bearing surface of the chip. Such solder regions may also be formed on corresponding contact pads on the PCB. Then, a flux is applied to the solder regions on the chip and/or to the corresponding contact pads and/or corresponding solder regions on the PCB in order to remove oxide layers which may have formed on these solder regions or contact pads and to achieve increased wetting of the contact pads by the solder regions. Thereafter, with the circuit-bearing surface of the chip facing the PCB, the solder regions on the chip are brought into contact with the corresponding contact pads or solder regions on the PCB, and the resulting assembly is heated in order to melt, and thereby reflow, the solder regions on the chip and/or the PCB. Upon cooling and re-solidification, solder connections between the chip and the PCB result.
In a manner similar to that described above, one method for mounting a module, e.g., an organic module or a ceramic module, bearing semiconductor chips (hereinafter denominated a chip carrier module or just module) onto a PCB, involves forming, e.g., screening, regions of solder onto contact pads on the non-chip-bearing surface of the module. Such solder regions may also be formed on corresponding contact pads on the PCB. A flux is then applied to the solder regions on the module and/or the corresponding contact pads and/or corresponding solder regions on the PCB. Thereafter, with the non-chip-bearing surface of the module facing the PCB, the solder regions on the module are brought into contact with the corresponding contact pads or solder regions on the PCB and the resulting assembly is heated in order to melt, and thereby reflow, the solder regions on the chip and/or the PCB. Upon cooling and re-solidification, solder connections between the module and the PCB result.
If the module of interest has electrically conductive pins extending from the non-chip-bearing surface of the module, then the module is mounted onto a PCB by, for example, initially positioning the module over the top (i.e., the circuit-bearing) surface of the printed circuit board and inserting the electrically conductive pins of the module into corresponding, copper plated through holes (PTHs) extending through the thickness of the PCB. Then, the PCB and the module are placed on a conveyor, which passes the PCB and module over a fluxing wave or flux sprayer, which serves to impinge liquid flux onto the bottom surface of the PCB and into the PTHs. This flux is wicked up into the PTHs, and thus flux is applied to both the walls of the PTHs and to the pins extending into the PTHs. Thereafter, the conveyor passes the PCB and module over a solder wave, which serves to impinge liquid solder onto the bottom surface of the PCB and into the PTHs. This liquid solder is also wicked up into the PTHs, filling the PTHs and, upon cooling and solidification, serving to encapsulate the pins within the PTHs.
One of the most important aspects of the above-described chip-mounting and module-mounting procedures is the choice of flux. That is, as noted above, the flux serves to remove any oxide layers which may have formed on the solder regions, contact pads, pins or PTHs and to increase the wetting of, for example, contact pads by solder regions. A problem with commonly available fluxes is degraded flux components that interfere with underfill adhesion in soldered connections. The underfill adhesion is provided by a liquid adhesive having a low viscosity that is applied to soldered connections, such as those between chips and chip carriers, to fill in underneath for greater strength. Another problem is that, in most instances, at the completion of the soldering process, use of the commonly available fluxes results in ionic residues remaining on the solder regions, contact pads, pins or PTHs Such ionic residues are undesirable because they lead to corrosion of circuitry and to short circuits. Consequently, if formed, such ionic residues must be removed, e.g., cleaned with water, after the completion of the soldering process.
The solder connections formed between a chip and a PCB or between a pinless module and a PCB, as described above, have relatively small heights, e.g., 4 mils, and therefore the spacing between a chip or pinless module and its PCB is correspondingly small. This is significant because it implies that it would be very difficult, if not impossible, to clear away any ionic residues remaining on the solder regions and/or contact pads after the completion of the soldering process. In addition, in the case of a pinned module, while corresponding ionic residues are readily cleaned with water, one must then deal with the environmental hazards posed by the resulting contaminated water.
Significantly, those engaged in the development of fluxes and soldering processes for mounting chips and modules onto PCBs have sought no-clean fluxes, which leave essentially no ionic residues on solder regions, contact pads, pins or PTHs at the completion of the corresponding soldering processes. As is described in U.S. Pat. No. 5,531,838, one no-clean flux includes pimelic acid, HOOC(CH
2
)
5
COOH, as the primary active ingredient, and two organic solvents, one with a relatively low evaporation temperature and one with a relatively high evaporation temperature.
No-clean fluxes are typically formulated to provide for complete volatility during reflux. As a consequence of this requirement, the active ingredients of the fluxes usually consist of weakly active volatile carboxylic acids dissolved in non-active volatile solvents. These fluxes may work very well as long as surface oxide thickness is kept to a minimum. However, when thicker oxides are present, such as those encountered with electrodeposited solders, significant non-wets may be observed. Furthermore, addition to these fluxes of typical activators, such as chlorinated or brominated amines or alcohols, results in residues which might not be tolerable.
SUMMARY OF THE INVENTION
By the present invention, a composition is provided which has an activator which enhances the solder wetting properties of a dicarboxylic acid and is completely volatile in a typical reflow profile. As a result, non-wets when plated solders are used are reduced to acceptable levels, while the low residue property of the flux is preserved.
More specifically, a low concentration of acetic acid, in the range of about 2% to about 4%, is added to a flux solvent system containing a dicarboxylic acid, such as adipic, pimelic or sebacic. Acetic acid, by itself in the solvent system, does not have noticeable fluxing characteristics. Glacial acetic acid can serve as a flux, but heavy residues of lead around the solder sites are usually obtained. Such residues can be detrimental to the electrical properties. However, when acetic acid is added to a flux containing a dicarboxylic acid, it acts as a precursor to the formation of the higher molecular weight carboxylate lead and tin salts. The result is that a more complete reaction is achieved with deeper oxides and, as the temperature is raised during the reflux profile, the acetate ion is replaced by the higher molecular weight species.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT(S)
The invention involves a flux composition which leaves essentially no ionic residues at the completion of conventional soldering processes used to mount electronic
Henderson Donald W.
Spalik James
Combs Morillo Janelle
Fraley Lawrence R.
Wyszomierski George
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