Composition for detecting uranyl

Chemistry: analytical and immunological testing – Composition for standardization – calibration – simulation,...

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436 58, 436 73, 436164, 436903, 436904, G01N 2100

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active

054242118

ABSTRACT:
A composition for detecting the presence and concentration of a substance such as uranyl, comprising an organohalide covalently bonded to an indicator for said substance. The composition has at least one active OH site for forming a complex with the substance to be detected. The composition is made by reacting equimolar amounts of the indicator and the organohalide in a polar organic solvent. The absorbance spectrum of the composition-uranyl complex is shifted with respect to the absorbance spectrum of the indicator-uranyl complex, to provide better spectral resolution for detecting uranyl.

REFERENCES:
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patent: 4320093 (1982-03-01), Volesky et al.
patent: 4349350 (1982-09-01), Fitoussi et al.
patent: 4511660 (1985-04-01), Lubbers et al.
Kanicky, V. et al. "The reaction of uranyl (2+) ion with chromazurol S and the spectrophotometric determination of uranium in the presence of Septonex." Collect. Czech. Chem. Comm. (1980), 45(5), 1525-54.
S. B. Savvin, Analytical Use Of Arsenazo III, Tatana 1961 vol. 8, pp. 673 to 685, Apr. 20, 1961.
S. B. Savvin, Photometric Determination Of Thorium and Uranium With Arsenazo III Reagent, Apr. 15, 1959.

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