Compositions: coating or plastic – Coating or plastic compositions – Heavy metal compound containing
Patent
1996-06-10
1997-07-08
Brunsman, David
Compositions: coating or plastic
Coating or plastic compositions
Heavy metal compound containing
501137, 427226, C04B 3546
Patent
active
056456344
ABSTRACT:
A composition comprising Ba and Sr salts of carboxylic acids represented by the formula: C.sub.n H.sub.2n+1 COOH wherein 3.ltoreq.n.ltoreq.7, and having structures represented by the following formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represent a hydrogen atom, a methyl group or an ethyl group, and M represents Ba or Sr, can be used to form thin films of Ba.sub.1-x Sr.sub.x Ti.sub.y O.sub.3. A composition comprising a barium carboxylate, a strontium carboxylate and a titanium alkoxide in a mixed solvent of a carboxylic acid and an ester, can also be used to form Ba.sub.1-x Sr.sub.x Ti.sub.y O.sub.3 thin films. The proportion of the mixed solvent is 2-11 molar times as much as the Ti. A composition comprising salts of carboxylic acids represented by R.sup.a COOH wherein R.sup.a is a linear or branched alkyl group having 3-7 carbon atoms, as the Ba and Sr sources, and Ti(OR.sup.b).sub.4 wherein R.sup.b is a linear or branched alkyl group having 1-7 carbon atoms, as the Ti source, can also be used to form thin films of Ba.sub.1-x Sr.sub.x TiO.sub.3.
REFERENCES:
patent: 4886654 (1989-12-01), Ohga et al.
patent: 4937213 (1990-06-01), Bernier et al.
patent: 5368834 (1994-11-01), Kulwicki et al.
patent: 5443746 (1995-08-01), Harris et al.
Atsuki Tsutomu
Endo Keiko
Ogi Katumi
Yonezawa Tadashi
Brunsman David
Mitsubishi Materials Corporation
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