Composite rocket propellant composition with a controllable pres

Explosive and thermic compositions or charges – Particle size of a component – Organic fuel

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149 193, 149 196, 149 1991, 149 20, C06B 4510

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active

050592602

ABSTRACT:
Gem-difluoroamino compounds are employed as a partial or complete replacement for TVOPA (trisvinoxypropyl adduct), tris-1,2,3-[bis(1,2-difluoroamino)-ethoxy]propane, in accordance with the nomenclature established by the International Union of Pure and Applied Chemistry. A partial or complete replacement of the vicinal-(1,2-)difluoroamino plasticizer of a difluoroamino-based propellant with its structural isomer or a related structural isomer, namely, a geminal-(1,1-)bis-difluoroamino compound has resulted in two beneficial effects, namely, a marked reduction in pressure exponent and an enhancement of the burning rate of the propellant. Representative of the geminal compounds are the compounds identified as SYEP and SYPO and further identified by the following structural formulas and chemical nomenclatures:
SYEP

REFERENCES:
patent: 3764417 (1973-10-01), Hill et al.
patent: 3813305 (1974-05-01), Baldwin et al.
patent: 3878002 (1975-04-01), Baldwin
patent: 3914139 (1975-10-01), Jones et al.
patent: 3932241 (1976-01-01), Sayles
patent: 3933542 (1976-01-01), Childs et al.
patent: 4001057 (1977-01-01), Baldwin et al.
patent: 4072546 (1978-02-01), Winer
patent: 4078953 (1978-03-01), Sayles
patent: 4133706 (1979-01-01), Shoults
"SYFO Plasticizer Pilot Process", pp. 11-15 and 75, Report #RPL-TR-75-19, ted Apr. 1975, declassified on Dec. 31, 1978.

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