Pipes and tubular conduits – Flexible – Braided – interlaced – knitted or woven
Reexamination Certificate
2003-01-23
2004-07-06
Hook, James (Department: 3752)
Pipes and tubular conduits
Flexible
Braided, interlaced, knitted or woven
C138S137000, C138S141000, C138SDIG003, C428S036910, C428S036200
Reexamination Certificate
active
06758245
ABSTRACT:
BACKGROUND OF THE INVENTION
FIELD OF THE INVENTION
The invention relates to a composite pipe having a polytetrafluoroethylene (PTFE) inner layer and a covering layer of fiber-reinforced plastics material, which are joined to one another by force-locking and form-locking through an intermediate layer. A force-locking connection is one which connects two elements together by force external to the elements, as opposed to a form-locking connection which is provided by the shapes of the elements themselves.
In the chemical industry in particular, composite pipes which include an inner layer and a covering layer are used for transportation of liquids and gases.
A thermoplastic plastics pipe is used in that case as the inner layer. The plastics material is chosen on the basis of the properties of the medium for transportation. Plastics pipes made of polypropylene (PP), polyvinyl chloride (PVC) and polyvinylidene fluoride (PVDF) are currently those chiefly employed. Due to the increasing requirements of safety and performance, higher resistance to heat and to media is required of the thermoplastic materials being employed. Those increasing requirements are met by completely fluorinated plastics, such as perfluoroethylenepropylene (FEP), perfluoroalkoxytetrafluoroethylene (PFA) or also polytetrafluoroethylene (PTFE). PTFE has a particular role in that case due to its favorable price.
The wall thickness of an inner layer formed from such a plastics pipe is about 2 to 8 mm. Such a plastics pipe can only accommodate a slightly increased pressure, especially at higher temperatures. It is therefore necessary to provide the thermoplastic plastics pipes with a supporting covering layer which includes a thermosetting plastics material reinforced with glass or carbon fibers.
That supporting covering layer of reinforced thermosetting plastics material only undergoes intimate bonding with the thermoplastic inner layer upon an additional outlay. Various intermediate layers are used in order to nevertheless achieve adequate adhesive and shear strengths between the inner and covering layers. According to DIN (
German Standards Institution
) 16 964, the following adhesive shear strengths in segment shear tests (method B) are required for composite pipes with a thermoplastic inner layer:
Material of the
Adhesive shear strength
inner layer
[N/mm
2
]
PVC
7
PE-HD
2.5
PP
3.5
PVDF
5
Pipes of various thermoplastic plastics, for example PVC, polyamide, acrylic resins, polycarbonates, etc. are mentioned as an inner layer in Patent Abstracts of Japan, Publication No. 02035287 A. Those thermoplastic plastics pipes are adhesively joined to the thermosetting covering layer of the composite pipe, e.g. with the aid of isophthalic acid resins. The isophthalic acid resins include compounds which contain an isocyanate group. The disadvantage of that process is that PTFE in general cannot be adhesively joined.
If the pipes of the inner layer are made of polyolefins, in the normal case a glass fiber woven fabric is chosen as the intermediate layer. That glass fiber woven fabric is anchored mechanically to the surface of the inner layer. In practice, the anchoring is achieved by melting the surface of the polyolefin pipes which form the inner layer and partly embedding in that molten surface a continuous glass woven tape under tension and spirally with respect to the longitudinal axis of the pipe. The part of the fiber woven fabric projecting out of the surface of the inner layer is then wetted with the reactive resin required for the supporting covering layer. Thereafter, the covering layer is produced from the glass fibers impregnated with plastics material. In the following step the covering layer completely cures together with the intermediate layer. That structure is described in Works Standard 1250, part 2 of the firm Bayer AG. German Published, Non-Prosecuted Patent Application DE 198 41 121 A1 describes an intermediate layer which includes thermoplastic plastics fibers in addition to the glass fibers. Woven fabric produced from the two types of fiber is introduced into the intermediate layer. The plastics material of the thermoplastic plastics fibers is chosen in such a way that it can be welded with the plastics material of the inner layer of the composite pipe. As a result thereof, for example if polypropylene inner layers are employed, composite pipes with twice the adhesive shear strengths of composite pipes with an intermediate layer which includes only glass fiber woven tape, can be produced. However, the resistance of those inner layer materials to heat and media is not sufficient in many types of use in the chemical industry.
In the case of partly fluorinated plastics material, such as PVDF, inner layers with an activated surface (“etched pipes”) are conventionally employed in order to achieve an adhesive action with the covering layer. The melting of glass woven tape into the surface of the PVDF inner layer is expensive and is therefore avoided in the normal case.
Due to the high heat resistance of completely fluorinated polymers, in the case of that class of plastics it is even far more expensive to apply a glass woven tape. Inner pipes of comparatively inexpensive PTFE represent a particular problem in that case, since the melt viscosity required for the embedding is very high for that type of material. The individual crystallites in the PTFE indeed melt above a certain temperature, but in macromechanical terms no liquefaction takes place, and rather the PTFE decomposes as the temperature is increased further. If embedding of the fibers is successful in spite of the low melt viscosity, only low shear strengths between the PTFE body and fiber product are achieved. Thus, with specimens produced in that manner it has been possible to measure shear strengths of only about 1 N/mm
2
, which are therefore far below the strengths required according to DIN 16 964. Chemical treatment of the surface in the case of PTFE pipes is also not possible in the normal case for reasons of environmental incompatibility, and furthermore it has not been possible to achieve higher strengths with that process. Adhesive joining of the inner layer and covering layer likewise is not possible because of the antiadhesive behavior of the materials.
SUMMARY OF THE INVENTION
It is accordingly an object of the invention to provide a composite pipe having a PTFE inner layer and a covering layer of a fiber-reinforced plastics material, which overcomes the hereinafore-mentioned disadvantages of the heretofore-known products of this general type and in which adhesive and shear strength between the inner layer of PTFE and the covering layer of fiber-reinforced plastics material is improved considerably.
With the foregoing and other objects in view there is provided, in accordance with the invention, a composite pipe, comprising a PTFE inner layer, a covering layer of fiber-reinforced plastics material, and an intermediate layer force-lockingly and form-lockingly joining the inner layer and the covering layer to one another. The intermediate layer has two sides, a surface of PFA on one of the sides and a glass or carbon fiber textile product on the other of the sides.
Therefore, the object of the invention is achieved by providing a composite pipe which employs a special intermediate layer between the inner layer and the covering layer, instead of a surface treatment of the PTFE inner layer or instead of an adhesive joining or instead of an embedding of a glass fiber woven fabric on the surface of the inner layer. This intermediate layer includes PFA on the side facing the inner layer and textile glass or carbon fiber products, preferably of woven fabric, on the side facing the covering layer.
The PFA of the intermediate layer can be welded particularly well with the outer surface of the PTFE inner layer. This is because of the similar chemical make-up of the two fluorine-containing plastics materials and temperature ranges for the melting or sintering which lie close to one another or overlap. Since the joining of the PTFE inner l
Schmidt Willibald
Troschitz Ralf
Weisenfeld Heribert
Greenberg Laurence A.
Hook James
Locher Ralph E.
SGL Carbon AG
Stemer Werner H.
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