Composite of polyamide bonded to rubber and method for making th

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Rod – strand – filament or fiber

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156110A, 156315, 156330, 156331, 4274071, 428414, 4284769, 4284763, B32B 2734

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active

042594049

ABSTRACT:
Rubber compounds are readily bonded to nylon or polyamides, particularly tire cords of polyamides in which a high proportion of the amide linkages are attached directly to aromatic rings, using a two-step dip process in which the first dip comprises a liquid dispersion or solution of an epoxide having an average of from about two to four epoxide groups per molecule and a molecular weight up to about 600 and the second dip comprises an aqueous dispersion of a mixture of a major amount of a rubbery vinyl pyridine copolymer and a minor amount of a heat reactable 2,6-bis(2,4-dihydroxy phenylmethyl)-4-chlorophenol composition. High H-adhesions are obtained with this process. It is particularly useful for the bonding to rubber compounds of crystalline polyamides having a large number of aromatic groups in the polymeric structure, e.g., "Fiber B".

REFERENCES:
patent: 2902398 (1959-09-01), Schroeder
patent: 3063966 (1962-11-01), Kwolek et al.
patent: 3111448 (1963-11-01), Tawney
patent: 3247043 (1966-04-01), Cardina
patent: 3423230 (1969-01-01), Georges
patent: 3660202 (1972-05-01), Edington et al.
patent: 3861980 (1975-01-01), Wise

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