Composite materials having a low shrinkage force

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

Reexamination Certificate

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Details

C523S117000, C524S493000, C524S494000, C433S228100

Reexamination Certificate

active

07601767

ABSTRACT:
For composite materials having a total filler content of 80 to 95% by weight, containingA) 0.5 to 10% by weight of non-agglomerated nanofillers having particle sizes of 1 to 50 nm in the filler component,B) at least 60% by weight of a filler mixture of 50 to 90% coarse-particle and 10 to 50% fine-particle dental glass in the filler component, having a size ratio, relative to the average particle size (d50value), of coarse to fine particles of >1:4 to 1:30,C) as monomer component, a monomer mixture ofi. 60 to 80% bis-GMA or TCD-di-HEMA or TCD-di-HEA,ii. 10 to 18% UDMA,iii. Residual TEDMA and/or multifunctional crosslinkers,D) up to 1% photoinitiator(s); andE) optionally, at least one additional dental glass in the filler component having a different particle size than the coarse- and fine-particle dental glass,the polymerization shrinkage may be reduced to <1.6% by volume (measured according to the bonded disk method; Dental Materials (2004) 20, 88-95), andthe shrinkage force (measured according to the photoelastic method; Dental Materials (2004) 20, 313-321) may be reduced to <3.5 MPa (measured 24 hours after polymerization).

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