Composite materials

Details Composite materials Composite materials

1997-05-21

1999-07-13

Weisberger, Richard

Stock material or miscellaneous articles

Coated or structually defined flake, particle, cell, strand,...

Rod, strand, filament or fiber

428373, 428374, 428379, 428389, 428397, 428605, 428607, 428368, 428387, 428367, 428388, B32B 900, B32B 1514, C22C 109

Patent

active

059224606

DESCRIPTION:

BRIEF SUMMARY
The present invention relates to matrix composite materials and more particularly relates to a coating for the materials.
It is known to prepare composites comprising a fiber reinforcement in a metal matrix. The presence of fibers reduces or prevents the propagation of cracks in the material and is an effective method of increasing the elastic strength and toughness of a material. The resultant materials are characterised by high strength and stiffness and light weight which make them useful for fabrication of aircraft structures, deep sea pressure vessels and other like applications. Thus, continuous silicon carbide fibre reinforced metal matrix composite materials offer advantages over conventional monolithic materials.
However there is a need to fabricate a protective coating or layer for the fiber to reduce or prevent interfacial chemical or other types of microstructural degradation. The present invention relates to an improved coating for silicon carbide fibres in a metal matrix composite material.
Thus according to the present invention there is provided a matrix composite material comprising a fibre reinforcement, the fiber reinforcement having a coating comprising gadolinium and gadolinium boride.
It is desirable that the fiber coating is capable of accommodating the strains imposed between the fiber and the matrix caused by the differences in coefficient of thermal expansion and hence reduce the risk of matrix cracking or coating fracture. Also the coating is desirably capable of preventing or reducing the transport of reactant material from the matrix to the fiber thereby avoiding chemical degradation of the fiber.
The fiber reinforcement may be any particulate, whisker, laminate, short or continuous fiber but is preferably ceramic and is most preferably silicon carbide. The matrix of the composite may be any metal containing material but is preferably a metal alloy, an intermetallic compound, or a ceramic. The preferred metal is titanium and may be in the form of a titanium alloy, an intermetallic compound such as titanium aluminide, TiAl or Ti.sub.3 Al, or a ceramic such as an oxide, carbide, boride or nitride. Other suitable materials include nickel containing materials. Intermetallic compounds tend to have good high temperature properties but are less damage tolerant, e.g. may be vulnerable to cracking, and thus are particularly suitable for the coating of the present invention.
The coating preferably comprises a gadolinium layer having a thickness of 1 to 6 microns and a gadolinium boride layer having a thickness of 1 to 6 microns. The gadolinium boride has a composition GdB.sub.x where x is in the range 2 to 6. In the case of titanium based metal matrix composites, the gadolinium layer is preferably formed adjacent to the fiber.
The coating can be applied to the fibers by a variety of known techniques such as electrodeposition, sputtering etc but the preferred technique is by use of electron beam deposition.
The invention also includes a method of fabricating a matrix composite material comprising the steps of (a) coating SiC fibers with gadolinium by use of a deposition technique (b) further coating the fibers with gadolinium boride by use of a deposition technique and (c) consolidating the coated fibers into a matrix by means of a suitable consolidation technique to form the matrix composite.
The deposition technique may be by use of electron beam deposition. The consolidation technique may comprise hot pressing. It is preferred that for titanium based matrix composites the first coating on the SiC fiber is gadolinium.
The invention will now be described by way of example only and with reference to the accompanying drawing.
The FIGURE shows a diagrammatic drawing of the experimental arrangement for coating SiC fiber with a duplex layer of gadolinium and gadolinium boride.
The fiber 1 were mounted in a cylindrical array on a rotatable fibre carrier 2. The carrier was located above a Temescal CV14 electron-beam (EB) heated double evaporation source 3 and was rotated at 300 r.p.m. The gadol

REFERENCES:
patent: 4853294 (1989-08-01), Everett et al.
patent: 5162159 (1992-11-01), Tenhover et al.
patent: 5273709 (1993-12-01), Halverson et al.
patent: 5354615 (1994-10-01), Tenhover et al.

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