Composite catalyst for carbon monoxide and hydrocarbon oxidation

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon monoxide component

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4232453, 423247, 423437M, C01B 3118, C01B 3120, B01D 5362, B01D 5372

Patent

active

055001980

ABSTRACT:
A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

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