Composite battery separator film and method of making same

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Separator – retainer or spacer insulating structure

Reexamination Certificate

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C429S249000, C429S251000, C429S252000, C429S254000

Reexamination Certificate

active

07989103

ABSTRACT:
A microporous separator film for electrochemical cells and a method of making such films is disclosed. The microporous separator film includes an intimate mixture of an electrically insulating matrix phase and a self-switching voltage activated conductive phase, wherein the voltage activated conductive phase provides a plurality of conductive paths from a first face of the microporous separator film to a second face of the microporous separator film. The method for making the composite microporous separator film includes the steps of forming an intimate mixture of at least an insulating matrix phase and a self-switching voltage activated phase, forming a film from the mixture, and generating pores within the film.

REFERENCES:
patent: 6148503 (2000-11-01), Delnick et al.
patent: 6228516 (2001-05-01), Denton
patent: 7321012 (2008-01-01), Sotzing
patent: 2004/0137331 (2004-07-01), Han et al.
patent: WO 03/100954 (2003-12-01), None
Thomas-Alyea, K. E.; Modeling the Behavior or Electroactive Polymers for Overcharge Protection . . . , Journal of The Electrochemical Society, vol. 151, Iss. 4, 2004, p. A509.
Chen, G.; Overcharge Protection for Rechargeable Lithium Batteries Using Electroactive Polymers, Electrochemical and Solid-State Letters, vol. 7, Iss. 2, 2004, p. A23.
Chen, G.; Overcharge Protection for High Voltage Lithium Cells Using Two Electroactive Polymers, Electrochemical and Solid-State Letters, vol. 9, Iss. 1, 2006, p. A24.
Xiao, L. F.; A composite polymer membrane with reversible overcharge protection mechanism for lithium ion batteries, Electrochemistry Communications, vol. 7, 2005, p. 589.
PCT Search Report & Op., (issued Aug. 30, 2007 for PCT/US06/28416).

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