Components and catalysts for the polymerization of olefins

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502102, 502103, 502118, 502125, B01J 3100

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active

060488182

ABSTRACT:
The present invention relates to a solid catalyst component for the polymerization of olefins CH.sub.2 .dbd.CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising a titanium compound, having at least a Ti-halogen bond and an electron donor compound supported on a Mg halide, in which said electron donor compound is selected from esters of malonic acids of formula (I): ##STR1## wherein R.sub.1 is a C.sub.5 -C.sub.20 linear or branched alkyl, a C.sub.5 -C.sub.20 cycloalkyl, a C.sub.7 -C.sub.20 arylalkyl or alkylaryl group; R.sub.2 and R.sub.3, equal to or different from each other, are C.sub.1 -C.sub.3 alkyl, cycloalkyl. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give high yields and polymers having high insolubility in xylene.

REFERENCES:
patent: 4220554 (1980-09-01), Scata et al.
patent: 4298718 (1981-11-01), Mayr et al.
patent: 4399054 (1983-08-01), Ferraris et al.
patent: 4495338 (1985-01-01), Mayr et al.
patent: 5583188 (1996-12-01), Kashiwa et al.
patent: 5606008 (1997-02-01), Sakashita et al.

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