Complexes of N-methylolacrylamides with polyalkoxylates and poly

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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252351, 252357, 252DIG1, 524555, 524827, 525187, 525 56, 525530, 526209, 526911, C08L 3324, C08G 6948

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active

043931731

ABSTRACT:
A composition of matter comprising (1) an N-methylol monomer of the following general formula: ##STR1## wherein R is hydrogen, lower alkyl (C.sub.1 -C.sub.4), isopropenyl, or phenyl and R.sub.1 is hydrogen or methyl, and (2) a polyalkoxylate substance having at least a portion of its structure represented by (alkylene oxide).sub.x, wherein x is an integer, the composition containing about x molecules of the N-methylol monomer per molecule of polyalkoxylated substance. Such N-methylol monomer/polyalkoxylated complexes are polymerized to yield ungelled cross-linkable N-methylol polymers. The N-methylol polymers are cross-linked in a controlled manner with polyvinyl alcohol.

REFERENCES:
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patent: 3300439 (1967-01-01), Chloupek et al.
patent: 3732184 (1973-05-01), Lindemann et al.
patent: 4044197 (1977-08-01), Wiest et al.
F. E. Bailey, Jr. et al., Journal of Polymer Science: Part A, vol. 2, 845-851, (1964).
N. G. Gaylord in "Matrix Polymerization and the Effects of Polymers on Grafting" published in Block and Graft Copolymers, J. J. Burke and V. Weiss, Eds., Syracuse University Press, 1973, pp. 19-50.
H. Kamogawa and T. Sekiya, Journal of the Chemical Society of Japan, Industrial Chemistry Section, 63 (9), 1631-1635, Sep. 1960.

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