Complexes of carbon nanotubes and fullerenes with...

Chemistry of inorganic compounds – Carbon or compound thereof – Elemental carbon

Reexamination Certificate

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C423S461000, C423S44500R, C977S845000, C977S847000, C106S287200, C548S416000, C548S415000, C438S099000, C455S125000

Reexamination Certificate

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07867469

ABSTRACT:
Separation of carbon nanotubes or fullerenes according to diameter through non-covalent pi-pi interaction with molecular clips is provided. Molecular clips are prepared by Diels-Alder reaction of polyacenes with a variety of dienophiles. The pi-pi complexes of carbon nanotubes with molecular clips are also used for selective placement of carbon nanotubes and fullerenes on substrates.

REFERENCES:
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patent: 2005/0074613 (2005-04-01), Tour et al.
patent: 2005/0207963 (2005-09-01), Tour et al.
patent: 2006/0115640 (2006-06-01), Yodh et al.
patent: 2008/0085234 (2008-04-01), Phillips et al.
Boese et al. Synthesis and Supramolecular Structures of Molecular Clips; Tetrahedron; vol. 57, Issue 17, pp. 3673-3687; 2001.
“Dynamic supramolecular porphyrin systems,”Tetrahedron61 (2005), 13-41, to Satake et al.
“Hydrogen-Bonding-Driven Preorganized Zinc Porphyrin Receptors for Efficient Complexation of C60, C70, and C60Derivaties,”J. Am. Chem. Soc. 2005, 127 (49), 17460-17468, to Wu et al.
“Synthesis and supramolecular structures of molecular clips,”Tetrahedron 57(2001), 3673-3687, to Klärner et al.

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