Complex oxide having n-type thermoelectric characteristics

Batteries: thermoelectric and photoelectric – Thermoelectric – Having particular thermoelectric composition

Reexamination Certificate

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C257S043000, C423S593100

Reexamination Certificate

active

10507868

ABSTRACT:
The present invention provides a complex oxide having a composition represented by the formula La1−xMxNiO2.7−3.3or (La1−xMx)2NiO3.6−4.4(wherein M is at least one element selected from the group consisting of Na, K, Li, Zn, Pb, Ba, Ca, Al, Nd, Bi and Y, and 0.01≦×≦0.8), the complex oxide having a negative Seebeck coefficient at 100° C. or higher. This complex oxide is a novel material which exhibits excellent properties as an n-type thermoelectric material.

REFERENCES:
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patent: 5728481 (1998-03-01), Kasai et al.
patent: 2001/0016554 (2001-08-01), Takeuchi
patent: 08-229355 (1996-09-01), None
patent: 2000-211971 (2000-08-01), None
CAPLUS entry for Savchenko et al. (Synthesis and electric properties of solid from the lanthanum sesquioxide-nickel monoxide-barium oxide system, lzvestiya Akademii Nauk SSR, Neorganicheskie Materialy (1987), 23(6), 973-6).
CAPLUS entry for Rao et al (A comparative study of the magnetic and electrical properties of perovskite oxides and the corresponsing two-dimensional oxides of dipotassium tetrafluoronickelate structure, Journal of Solid State Chemistry (1988), 72(1), 14-23).
CAPLUS entry for Ganguli et al. (“Elusive superconductivity in polycrystalline samples of layered lanthanum nickelates,” Solid State Communications (1989), 72(2), 195-7).

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