Complex-forming polymers and processes to prepare them

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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526265, 526259, C08F 830

Patent

active

049102648

ABSTRACT:
The invention is a complex-forming polymer comprising at least one aryl group having a 2,2'-bipyridine complex-forming moiety or a 1,10-phenanthroline complex-forming moiety. The complex-forming polymers are prepared by contacting a substituted 2,2'-bipyridine or a substituted 1,10-phenanthroline compound with a metalating agent, and then reacting the metalated compound with an halomethylated polystyrene polymer, or alternatively, reacting the metalated compound with at least one vinylbenzyl halide and subsequently polymerizing the reaction product. The complex-forming polymers are hydrolytically stable and may be used as polymeric ligands as such or complexed with selected metal compounds.

REFERENCES:
patent: 3436395 (1969-04-01), Ennis et al.
patent: 3810888 (1974-05-01), Chapuriat
patent: 4158093 (1979-06-01), Bailey et al.
patent: 4188395 (1980-02-01), Bossert et al.
patent: 4424359 (1984-01-01), Kaschig et al.
Three-Phase Test. Detection of Free Cyclobutadiene by Julius Rebek, Jr. and F. Gavina, Sep. 11, 1974.
Poly(styryl)bipyridine: Synthesis and Formation of Transition-Metal Complexes . . . by Roger J. Card and Douglas C. Neckers, 11-23-77.

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