Complex compounds containing sulfonated phenyl phosphanes

Details Complex compounds containing sulfonated phenyl phosphanes Complex compounds containing sulfonated phenyl phosphanes

1992-01-21

1992-10-13

Raymond, Richard L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

564374, 564408, 564509, C07C20960

Patent

active

051552744

ABSTRACT:
New complexes of the elements of Groups VIIA, VIIIA, and IB of the Periodic Table* with the trisodium salt of tris(m-sulfophenyl)phosphane as a complex ligand. The complexes are used as catalysts for hydrogenations for the water gas reactions, hydrocarbonyls, hydroformylations, oxidations, carbon-carbon cross-linking reactions (e.g. allene/alkine coupling), and additions of secondary amines to carbon-carbon double bonds.

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Escaffre et al., J. Chem. Soc., Chem. Commun., 1987 (3), pp. 146-7.
Kalck et al., Chemical Abstracts, vol. 110(14):117090k (1989).
Varre et al., Chemical Abstracts, vol. 105(15):134131p (1986).

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