Complex compounds containing sulfonated phenyl phosphanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 13, 556 16, 556 19, 556 20, 556 45, 556110, 556136, 556138, C07F 904, C07F 100, C07F 1500, C07F 1300

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active

050576186

ABSTRACT:
New complexes of the elements of Groups VIIA, VIIIA, and IB of the Periodic Table* with the trisodium salt of tris(m-sulfophenyl)phosphane as a complex ligand. The complexes are used as catalysts for hydrogenations for the water gas reactions, hydrocarbonyls, hydroformylations, oxidations, carbon-carbon cross-linking reactions (e.g. allene/alkine coupling), and additions of secondary amines to carbon-carbon double bonds.

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patent: 4442290 (1984-04-01), Hill et al.
patent: 4625069 (1986-11-01), Sieole et al.
patent: 4822915 (1989-04-01), Murray
patent: 4857235 (1989-08-01), Heggie et al.

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