Complex catalyst, process for producing the complex...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

Reexamination Certificate

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Reexamination Certificate

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06995110

ABSTRACT:
There are provided (asymmetric) complex catalysts comprising metal complexes and Lewis acids as components, the metal complex being of formula (1):wherein R1, R2, R3, R4, R5, R6, R7and R8are the same or different and are independently hydrogen, halogen, alkyl or the like; one of R9and R10is hydrogen and the other is alkyl of 1 to 4 carbon atoms or the like; Q is a single bond or alkylene of 1 to 4 carbon atoms; M is a metal ion; and A is a balancing counter ion or ligand; processes for the production of these complex catalysts; processes for the production of (optically active) alcohol derivatives, characterized in that cyclic ether compounds are reacted with phenol derivatives in the presence of these complex catalysts; and further processes for producing (optically active) nitrogen-containing heterocyclic compounds by reacting these alcohol derivatives with halogenated nitrogen-containing heterocyclic compounds in the presence of a base.

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Q. Mingxing et al., “Ethylene oligomerization by diimine iron(II) complexes/EAO”,Journal of Molecular Catalysis A: Chemical, vol. 160, 2000, XP-002291190, pp. 243-247.
Patent Abstracts of Japan, vol. 0151, No. 63-(C-0826,Apr. 24, 1991, corresponding to JP-A 03-03451 published Feb. 14, 1991, to Sumitomo Chemical Co.
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