Compatible blend of polycarbonate with vinyl (co)polymer

Details Compatible blend of polycarbonate with vinyl (co)polymer Compatible blend of polycarbonate with vinyl (co)polymer

2002-01-18

2003-12-30

Buttner, David J. (Department: 1712)

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Mixing of two or more solid polymers; mixing of solid...

C525S133000, C525S146000, C525S148000

Reexamination Certificate

active

06670420

ABSTRACT:

The invention is directed to thermoplastic molding compositions and more particularly to a compatible blend containing polycarbonate and a vinyl (co)polymer.
SUMMARY OF THE INVENTION
A compatible blend of polycarbonate resin with a vinyl (co)polymer blending partner is disclosed. The preparation of inventive blend comprises reactive blending of polycarbonate, a vinyl (co)polymer and a novel compatibilizer in the presence of a transesterification catalyst and under conditions of time and temperature designed to promote transesterification. The compatibilizer is the polymerized reaction product of at least one vinyl monomer that contains no hydroxy groups and a hydroxyl containing monomer conforming to (I)
where R denotes H or C
1
-C
4
alkyl, R
1
denotes H, Cl, Br, C
1
-C
4
alkyl, cyclohexyl, or C
1
-C
4
alkoxy, a is 0 or 1, b is 0 or 1, c is 0 or 1, n is an integer of 0 to 4 and X is an OH group. The compatible blends of the invention are characterized by their improved properties.
BACKGROUND OF THE INVENTION
It has long been recognized that compatible heterogeneous resin blends having good properties are characterized by the presence of finely dispersed phase and resistance to phase separation. Various methods have been reported to successfully enhance compatibility (see Xanthos, M. and S. S. Dagli,
Compatibilization of Polymer Blends by Reactive Processing
, in
Polym. Eng. Sci.,
1991, p. 929-35 and the articles cited there for an overview of the technology.) Reactive processing has long been recognized as means for attaining compatibility of polymeric blending partners. Enhancement of compatibility is known to be attained by forming copolymers, using reactive processing, such as graft or block copolymers with segments capable of specific interactions and/or chemical reactions with the blend components that would otherwise be incompatible. The review article referred to above points to continuous reactive processing, in particular, extrusion, as means to providing compatibilization of polymer blends through reactions during compounding. U.S. Pat. No. 3,856,886 disclosed thermoplastic graft copolymers wherein polymeric backbone contains aromatic hydroxy groups and where aromatic polycarbonate is grafted onto the backbone via the aromatic hydroxy groups. The disclosed graft copolymers are said to form blends with polycarbonate and/or with polymers of olefinically unsaturated monomers.
Graft polycarbonates in which the graft stock is a vinyl polymer which contains side chains that contain hydroxyphenyl groups, on which aromatic polycarbonate chains are condensed, have been disclosed in U.S. Pat. No. 3,991,009. These, together with graft polymer rubbers, form thermoplastic molding composition.
U.S. Pat. No. 4,874,816 disclosed a process for the production of vinyl copolymers with grafted-on polycarbonate chains. These grafts are prepared through the reaction of biphenols and phosgene in an interfacial process with hydroxyl containing vinyl polymers.


REFERENCES:
patent: 3856886 (1974-12-01), Margotte et al.
patent: 3991009 (1976-11-01), Margotte et al.
patent: 4874816 (1989-10-01), Dujardin et al.
patent: 5266635 (1993-11-01), Wilkey
patent: 01-315425 (1989-12-01), None
patent: 07-033929 (1995-02-01), None
Li, “Miscibility of Polymer Blends . . . ”Journal of Applied Polymer Science,Vol 74, p 639-646; Oct. 1999.*
Polymer Eng. Sci., vol. 31, Jul. 1991, pp. 929-935, M. Xanthos & S.S. Dagli, Compatibilization Of Polymer Blends by Reactive Processing.
Database CA [Online] Chemical Abstracts Service, Columbus, Ohio, US: retrieved from STN.
Database accession No. 123:171437/DN, HCAPLUS XP002185867 * abstract * IT 24936-68-3 * & JP 07 033929 A (Denki Kagaku Kogyo KK) Feb. 3, 1995.
Patent Abstracts of Japan vol. 014, No. 115 (c-0696), Mar. 5, 1990 & JP 01 315425 A (Tosoh Corp), Dec. 20, 1989 *abstract *.
Patent Abstracts of Japan, vol. 1998, No. 02, Jan. 30, 1998 & JP 09 279004 A (Asahi Chem Ind Co Ltd), Oct. 28, 1997 * abstract *.

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