Commercial production of transition metal sulfides from their ha

Chemistry of inorganic compounds – Sulfur or compound thereof – Binary compound

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C01B 1700

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042083940

ABSTRACT:
Sulfides of Group IVb and Vb transition metals are produced by reacting their halides with carbon disulfide. The reactions can be between liquid or gaseous halides and liquid or gaseous carbon disulfide. The reaction products are formed and recovered as solids and the other reaction product, carbon tetrahalide, is carried off as a gas and recovered. A specific example is the production of titanium disulfide by reacting titanium tetrachloride with carbon disulfide.

REFERENCES:
patent: 2556912 (1951-06-01), Gardner
patent: 3113977 (1963-12-01), Seitzer
Mellor, J. W., A Comprehensive Treatise on Inorganic & Theoretical Chemistry, Longmans & Green & Co., N.Y., N.Y., 1925, vol. VI, p. 114, vol. VII, pp. 90 & 91.

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