Combined hydrogenolysis plus oxidation process for sweetening a

Mineral oils: processes and products – Refining – Sweetening

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Details

208189, 208192, 208207, C10G 2700, C10G 2704

Patent

active

050645250

ABSTRACT:
This invention relates to a process for sweetening a sour hydrocarbon fraction. The process involves two steps. In one step the mercaptans in the sour hydrocarbon fraction are reacted with hydrogen in the presence of a selective hydrogenolysis catalyst to selectively hydrogenolyse the tertiary mercaptans. In another step, the mercaptans are oxidized by reacting them with an oxidizing agent in the presence of oxidation catalyst and a basic component. The selective hydrogenolysis step and the oxidation step may be carried out in any order, i.e., either hydrogenolysis first followed by oxidation or vice versa.

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