Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...
Patent
1992-05-22
1993-12-21
Michl, Paul R.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Mixing of two or more solid polymers; mixing of solid...
525386, C08F25500
Patent
active
052722120
DESCRIPTION:
BRIEF SUMMARY
TECHNICAL FIELD
The present invention relates to colored spherical fine particles, a process for their production and their applications. More particularly, the present invention relates to colored spherical fine particles comprising fine particles and a coloring agent uniformly dispersed therein, which can be used as or in coatings, inks, toners for developing electrostatic latent images, coloring agents for heat-sensitive transfer ink, etc., static charge-controlling agents, display materials, magnetic recording materials, and so forth, as well as to a process for their production and their applications.
BACKGROUND ART
Coloring agents are generally a powder of white or other color which is insoluble or difficultly soluble in water and organic substances, and fine wide applications as a coloring agent for ink, coating, plastic, etc. or as a functional material wherein the inherent property of coloring agents is utilized.
Coloring agents take the form of fine powder and their affinity to other substances, for example, organic polymers and organic solvents is therefore weak as compared to the cohesive force between the particles of the powder. This makes it very difficult to uniformly mix or disperse a coloring agent under ordinary mixing or dispersing conditions. Further, coloring agents tend to be reagglomerated and it is difficult to obtain a dispersion having long-term stability.
In order to solve the above problem, there were proposed a number of methods for uniformly mixing or dispersing a coloring agent with or in a solid or liquid base material by coating the surface of the coloring agent with a surfactant or a resin, or by treating said surface with a coupling agent, or by using a polymeric dispersing agent in combination.
In these methods, however, the number of process steps are larger, the operations are complicated and the effects are insufficient; thus, no satisfactory results have not yet been obtained.
Toners used for development of developing electrostatic latent images have heretofore been produced by a process which comprises dispersing, by melt-mixing, a coloring agent and other additives (e.g. static charge-controlling agent, offset-preventing agent, lubricant) in a thermoplastic resin, solidifying the dispersion, finely granulating the solid dispersion, followed by classification to obtain a product having desired particle diameters.
In order to improve the above processes for toner production by grinding, there were proposed various processes for toner production by emulsion or suspension polymerization [e.g. Japanese Patent Publication No. 10231/1961, Japanese Patent Application Kokai (Laid-Open) No. 11957/1988, Japanese Patent Application Kokai (Laid-Open) No. 266562/1987, Japanese Patent Application Kokai (Laid-Open) No. 59242/1989].
These processes comprise adding to a polymerizable monomer a coloring substance (e.g. carbon black) and other additives (e.g. dispersing agent) and then conducting emulsion or suspension polymerization to produce a coloring agent-containing toner by one-stage polymerization.
In these processes, however, the coloring agent is not uniformly dispersed in the polymer particles and the toner properties are not satisfactory.
Further, there were investigated a process which uses a grafted carbon black obtained by graft-polymerizing a monomer component in the presence of carbon black (DT Patent No. 3102823), a process which uses a carbon black surface-treated with a polymer having an oxazoline group, an aziridine group or the like [Japanese Patent Application Kokai (Laid-Open) No. 156760/1989], and a process which comprises polymerizing a monomer in the presence of carbon black and a polymer having compatibility with a functional group present on the surface of the carbon black or having a reactive group (e.g. amino group) reactive with said functional group [e.g. Japanese Patent Application Kokai (Laid-Open) No. 50450/1984, Japanese Patent Application Kokai (Laid-Open) No. 67563/1987]. In these processes, however, the type of carbon black used is restrict
REFERENCES:
patent: 4331784 (1982-05-01), Ishibashi et al.
patent: 4412031 (1983-10-01), Kitihara
patent: 4536545 (1985-08-01), Olener et al.
patent: 4762892 (1988-08-01), Okano et al.
patent: 4806581 (1989-02-01), Walker
patent: 4829102 (1989-05-01), Biale
patent: 4885320 (1989-12-01), Biale
Cain Edward
Michl Paul R.
Nippon Zeon Co. Ltd.
LandOfFree
Colored spherical fine particles, process for production thereof does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Colored spherical fine particles, process for production thereof, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Colored spherical fine particles, process for production thereof will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-309728