Radiation imagery chemistry: process – composition – or product th – Radiation modifying product or process of making – Screen other than for cathode-ray tube
Reexamination Certificate
2000-06-14
2002-10-22
McPherson, John A. (Department: 2871)
Radiation imagery chemistry: process, composition, or product th
Radiation modifying product or process of making
Screen other than for cathode-ray tube
C347S106000
Reexamination Certificate
active
06468702
ABSTRACT:
CROSS REFERENCE
This application claims the benefit of Korean Patent Application No. 1999-22103 filed on Jun. 14, 1999, under 35 U.S.C. § 119, the entirety of which is hereby incorporated by reference.
BACKGROUND OF THE INVENTION
1. Field of the invention
The invention relates to a color filter for use in a liquid crystal display panel and a method of making the same.
2. Description of Related Art
Methods of making a color filter for a liquid crystal display panel or the like include a dyeing technique, a pigment dispersion technique, a printing technique and an electrodeposition technique.
In the dyeing technique, a photosensitive material is added to the water-soluble polymer material that is a dye material, sensitizing it to light. After this has been patterned through a lithographic process, it is steeped in a dye solution to obtain a colored pattern.
For example, first a black matrix that is an opaque portion is formed on a glass substrate. Then, the dye material, which is made by adding a photosensitive material to a. water-soluble polymer material so that the solubility in a solvent is reduced when exposed to light, is coated on the black matrix. Part of the dye material is exposed to light through a mask and developed, thus carrying out patterning so that the dye material remains only on the area of the first color. Sequentially, the dye material is steeped in dye solution to be dyed and then set to form the first color layer. This process is repeated three times to form a three-color filter.
Whereas a color filter made by the dyeing technique has a high transmissivity and bright colors, it is characterized by inferiority with respect to a light-resistance, a heat-resistance and a hygroscopicity.
In the pigment dispersion technique, a photosensitive resin in which a pigment has been dispersed is coated on a substrate, and this is patterned to obtain a single-color pattern; this process is then repeated. In the above dyeing technique, the dyeing process is carried out after patterning the dye material, whereas with the pigment dispersion technique a photosensitive resin that has already been colored is coated on the substrate. A color filter made by the pigment dispersion technique has a high durability but a somewhat reduced transmissivity.
Furthermore regarding the use of photosensitive resin, at least more than 70% of the amount of the photosensitive applied resin must be removed and disposed of, leading to a big problem in material efficiency. In the printing technique, paint made by dispersing pigment in thermosetting resin is applied by repeated printing to form three colors, respectively, and the resin is heat-cured to form the color layer. While the printing technique is simple, it is inferior in flatness.
In the electrodeposition technique, a patterned transparent electrode is provided on a substrate, and then this is immersed in an electrodeposition fluid containing a pigment, a resin, an electrolyte and so forth for electrodeposition of the first color. This process is repeated three times, and then finally baking is applied. The electrodeposition technique provides excellent flatness and is effective for color arrangement in a striped pattern, but is difficult to form a color arrangement in a mosaic pattern.
Of the techniques of manufacturing the color filter described above, the printing technique has a drawback in accuracy, and the electrodeposition technique has a drawback in terms of restrictions upon what sorts of images can be patterned. For such reasons, the dyeing technique and the pigment dispersion technique have been most widely used.
However, the dyeing technique and the pigment dispersion technique require a lithography step for forming the pixel regions of each of the first color, second color and third color, and this is a big obstacle to improve the a mass production efficiency of the color filter. One method for forming pixels without a lithography step for each color is an inkjet printing technique of making a color filter. Using an inkjet printing technique to form the pixels, the material efficiency is improved and the processing time becomes shorter, and moreover a color filter having a high brightness can be obtained.
The inkjet printing technique described above will be explained in detail hereinafter.
As shown in
FIG. 1A
, a black resin layer
20
and a water-repellent layer
22
are sequentially deposited on a substrate
1
. The black resin layer
20
serves as a black matrix, and the water-repellent layer
22
is made of fluorine-based material and serves to prevent the printing ink from overflowing in later process. Then, as shown in
FIG. 1B
, the black resin layer
20
and the water repellent layer
22
are patterned to form a black matrix
24
and a water-repellent film
26
, respectively. The water-repellent film
26
serves to isolate each of the colors from each other.
As shown in
FIG. 1C
, a certain color ink
30
of R (red), G (green) and B (blue) is sprayed individually upon corresponding isolated portions
25
between the water-repellent films
26
using a inkjet unit
28
. Such a printing process is repeated three times to form a color filter layer
31
of R, G and B as shown in FIG.
1
D. Finally, a passivation film
32
is formed on the whole surface of the substrate
1
while covering the color filter layer
1
, whereupon the color filter is completed.
However, for the inkjet-based method of manufacturing the color filter described above, the use of the water-repellent film significantly raises the production cost. Besides, since the water repellent layer (made of the fluorine-based material) is not photosensitive, a photoresist step should be additionally performed during the above patterning process, leading to a long processing time and a low yield.
SUMMARY OF THE INVENTION
An object of the present invention is to provide a color filter fabricated during a short processing time and a method of manufacturing the same.
In order to achieve the above object, the present invention provides a color filter for a liquid crystal display device, which includes: a black matrix formed on a substrate; a photosensitive water-repellent layer correspondingly formed on the black matrix; and a color filter layer formed on said substrate in openings within said water-repellent layer; wherein said water repellent layer has a wet angle greater than 60° with respect to said color filter layer.
The present invention further provides a method of manufacturing a color filter, which includes: forming a metal layer on a substrate; forming a water repellent layer on the metal layer; patterning simultaneously the metal layer and the water repellent layer using a predetermined mask to form a black matrix and a correspondingly-shaped water-repellent layer, the black matrix and the water-repellent layer forming isolated portions at openings within the water-repellent layer; and spraying three colors of ink into corresponding ones, respectively, of said isolated portions to form a color filter layer; wherein said water-repellent layer has a wet angle of greater than 60° with respect to said color filter layer.
The metal layer according to the present invention can have a dual layered structure, e.g., a CrOx layer and a Cr layer. The water-repellent layer can be benzocyclobutene (BCB).
The present invention further provides a method of manufacturing a color filter, which includes: forming a black matrix on a substrate; forming a water-repellent layer on the exposed substrate and the black matrix; irradiating the water-repellent layer from beneath the substrate using the black matrix as a mask; selectively removing irradiated portions of the water-repellent layer; and spraying three ink colors of ink into corresponding openings, respectively, within the black matrixes to form a color filter layer; wherein said water-repellent layer has a wet angle of greater than 60° with respect to said color filter layer.
Such methods according to the present invention can further comprise: removing the water-repellent layer and forming a transparent conductive
Kim Jeonghyun
Lee Jaekyun
Park Yongin
Yi Jonghoon
Birch & Stewart Kolasch & Birch, LLP
LG. Philips LCD Co. Ltd.
McPherson John A.
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