Cold bonded iron particulate pellets

Details Cold bonded iron particulate pellets Cold bonded iron particulate pellets

1999-11-01

2002-06-25

Jenkins, Daniel J. (Department: 1742)

Powder metallurgy processes

Powder metallurgy processes with heating or sintering

Metal and nonmetal in final product

Reexamination Certificate

active

06409964

ABSTRACT:

FIELD OF THE INVENTION
This invention relates to cold bonded pellets which contain a significant amount of an iron particulate material, which can be used as the feed material to a furnace for producing iron. The pellets are made from “iron particulate material”, which, in addition to referring to iron ore powder as such, for example haematite powder, sinter feed fines, sinter fines, and ore concentrate fines, also includes a wide variety of particulate materials derived from iron smelting processes which contain significant amounts of recoverable ferrous values, such as electric arc furnace (EAF) dust, basic oxygen furnace (BOF) dust, mill scale, and the like. At present, the use of at least some of these materials in commercial iron smelting techniques presents significant problems.
BACKGROUND OF THE INVENTION
Pellets containing particulate iron ore are used as a component of the feed in blast furnaces and DRI (direct reduced iron) furnaces. Commercially available iron ore pellets are formed by heat induration at temperatures of approximately 1300° C. However, the heat-induration method has a number of drawbacks: the cost of production is high due to capital and maintenance expenditures on high temperature furnaces, and large amounts of energy are needed for the high temperatures used.
Several attempts have been made to use iron ore fines in DRI furnaces, such as the Iron Carbide Process, in which the particle size of the iron ore used must fall within a range suitable for bed fluidization, i.e. 0.1 mm to 1.0 mm, with a tolerance of about 5%; and processes using coal-bearing pellets such as the FASTMET process, in which the fines used must have a size range that is suitable for making strong green pellets, i.e. <0.44 mm. However, these methods utilize only a narrow range of particle sizes, and therefore generate a significant amount of undersized waste. Several attempts have been made to develop a process for cold bonding iron ore pellets using either calcium silicate, limestone-silica, calcium carbonate, or organic glue as a binder, e.g. F.T.C. Doughty, “Operation of a New Pelletizing Process”, Iron and Steel International, December 1995; B. Hassler, “Control of the Properties of Cold-Bound Autoclaved Pellets”, Stahl und Eisen 95 (1975) Nr. 16. However, cold bonded iron ore pellets have not been commercially successful because the binders used are not heat resistant, and the pellets disintegrate when heated above 700° C., thus causing difficulties in the blast furnace environment.
It has also been proposed to use a Portland cement type binder to agglomerate iron ore powders using balling or briquetting techniques, for example in U.S. Pat. Nos. 3,264,090 and 4,846,884. In these methods, only a low amount of water is used, which appears to result in a product which is an outer shell bonded together by the cement binder, with more or less loose unbonded powder inside. These products have the disadvantage that the shells are not strong enough to withstand the blast furnace environment. An alternative complex process in which a binder comprising a mixture of styrene or acrylonitrile and vinyl polymers is used together with an aluminosilicate binder, such as Kayolite, and hydrochloric acid is described in U.S. Pat. No. 5,589,118.
Accordingly, it is desirable to develop a process which utilizes a broader range of iron ore particle sizes, and which also can be used to process particulate ferriferous materials other than ore powders, and in particular both EAF and BOF dusts.
SUMMARY OF THE INVENTION
Accordingly, this invention seeks to provide a process for producing cold bonded pellets suitable for use in iron smelting procedures, including blast furnaces and DRI furnaces, which are rugged enough to withstand the furnace environment.
This invention in its broadest embodiment provides a process, and the product of that process, in which an iron particulate material is mixed together with water and sufficient particulate high-alumina cement binder. The wetted mixture is then converted into shaped bodies such as pellets, briquettes, balls, and the like by conventional methods, or cast into moulds. After curing and drying, the shaped bodies can be fed to the furnace. Unlike at least some of the known process for producing, for example, pellets, it appears that almost any iron particulate material of a suitable size can be used in the process of this invention. The amount of binder used is adjusted to provide a shaped body such as a pellet, briquette or ball with adequate strength to withstand the aggressive conditions which exist in an iron producing furnace environment, especially blast and DRI furnaces. The amount of water used is adjusted to suit the shaping procedure used, but is always at least enough to ensure complete hydration, and consequently complete setting, of the high-alumina cement binder. This ensures that the cement bond extends throughout the final shaped product, thus avoiding the formation of a cemented shell with more or less loose powder material trapped inside. Ideally, the shaped bodies after the cement has set are a coherent mass throughout. With proper choice of both the amount of water, and the amount of cement binder, cured pellets with adequate mechanical strength to survive a furnace environment which will smelt adequately to provide iron can be obtained.


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Operation of a New Pelletising Process; F.T.C. Doughty; Iron and Steel International, Dec. 1975, pp 443-447.

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