Codimers of norbornadiene and alkynes

Details Codimers of norbornadiene and alkynes Codimers of norbornadiene and alkynes

1978-03-22

1979-10-02

O'Keefe, Veronica

Chemistry of hydrocarbon compounds

Compound or reaction product mixture

Alicyclic

1491094, 1491096, C07C 1328, C06B 4300, B01J 3112

Patent

active

041698630

ABSTRACT:
Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl alluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons are disclosed. After hydrogenation, resulting codimers can be used as high energy fuels or diluents for such fuels.

REFERENCES:
patent: 3345419 (1967-10-01), Tinsley et al.
T. Mitsudo et al. J. Chem. Soc. Chem. Comm. 1976, pp. 722-723.
I. Sasaki, J. Org. Chem. 37, No. 14, 1972.
Schrauzer et al., Chem. Ber. 97, pp. 2451-2452, 1964.
A. Carbonaro, Tetrahedron Letters, 49, pp. 5129-5130, 1965.

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