Codimer of norbornadiene and cyclohexadiene

Details Codimer of norbornadiene and cyclohexadiene Codimer of norbornadiene and cyclohexadiene

1979-04-17

1980-09-30

O'Keefe, Veronica

Chemistry of hydrocarbon compounds

Alicyclic compound synthesis

Polycyclic product

585362, 1491094, 60208, C07C 1328

Patent

active

042257360

ABSTRACT:
Novel codimer (I) of norbornadiene and 1,3-cyclohexadiene and its hydrogenated derivative (II), having the following structures: ##STR1## and processes for preparing both are disclosed. Product (II) can be used as a high energy fuel. Process for codimer I involves use of three component homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and one of three alkyl aluminum chlorides.

REFERENCES:
patent: 2831037 (1958-04-01), Schmerling
patent: 3258502 (1966-06-01), Cannell
patent: 3329732 (1967-07-01), Bastiau
patent: 4094916 (1978-06-01), Thomas
patent: 4094917 (1978-06-01), Thomas
Greco et al., J. Org. Chem., 35, No. 1, 271, 1970.
Carbonaro et al., J. Org. Chem., 36, No. 10, 1443, 1971.

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