Coating hollow containers by in-situ polymerization of monomers

Coating processes – Direct application of electrical – magnetic – wave – or... – Electrostatic charge – field – or force utilized

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427476, 427547, 427235, 427236, 427237, 4272556, B05D 512

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active

057076910

ABSTRACT:
Methods for providing a low permeability coating on the interior of a refillable plastic container, such as a PET beverage bottle, include coating of a liquid crystal polymer (LCP) by depositing LCP monomers on the interior surface of the container and bi-axially orienting the monomers continuously while reacting the monomers to produce the polymer. The interior surface of the container may be pre-treated to produce free radicals which enhance the attachment of the monomers to the surface. Also, the surface may be post-treated to eliminate unsaturated radicals or free monomers. The application of the monomers to the interior surface of the container can be effected by condensing a gas blend of monomers, by spraying liquid monomers or by filling with liquid monomers and then emptying to leave a residual coating. The monomers are reacted by preheating them or by subjecting them to a heated inert gas. To achieve the bi-axial orientation of the monomers, the interiorly coated container may be alternately subjected to longitudinal and circumferential magnetic fields while supported for incremental end-to-end rotation and rotation about its axis. Another technique for achieving the bi-axial orientation comprises subjecting the container to alternately applied longitudinal and circumferential electrostatic fields.

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