Coating composition with improved adhesion and method therefor

Coating processes – With cutting – holding – severing – or abrading the base – Prior to coating

Reexamination Certificate

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Details

C427S388200, C524S127000, C524S141000, C524S145000, C524S315000, C524S361000, C524S378000, C252S389230

Reexamination Certificate

active

06893680

ABSTRACT:
The invention relates to a coating composition demonstrating improved adhesion and method for improving adhesion of a coating composition to metal. The coating and method of the invention provide improved adhesion of a coating when coating is applied directly over metal substrates, especially untreated metal substrates such as galvanized steel, unsanded aluminum and unsanded cold-rolled steel. More particularly, the invention provides a composition comprising (I) an effective amount of a first compound having an acid number of from 70 to 120 mg KOH/g, a hydroxyl number of from 200 to 400 mg KOH/g, a number average molecular weight of from 300 to 700, and which is the reaction product of (a) at least one difunctional carboxylic acid, (b) at least one trifunctional polyol, (c) at least one chain stopper, and (d) phosphoric acid, (II) an effective amount of a second compound comprising a carboxy phosphate ester having the formula:wherein R is an C5-C40aliphatic group in which one or more aliphatic carbon atoms are substituted with lateral or terminal —COOR1groups, wherein R1is H, metal, ammonium, C1-C6alkyl, or C6-C10aryl, M is hydrogen, metal or ammonium and x is a number from 0 to 3, and (III) a compound providing low surface tension and promoting surface wetting of a substrate.

REFERENCES:
patent: 3415766 (1968-12-01), Jedlicka
patent: 3630790 (1971-12-01), Schmidt et al.
patent: 5021489 (1991-06-01), Knight et al.
patent: 5792806 (1998-08-01), Yamamoto et al.
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patent: 6458874 (2002-10-01), Newton
patent: 6534121 (2003-03-01), Newton et al.
patent: 6599965 (2003-07-01), Lane et al.
patent: 20040030088 (2004-02-01), Salter et al.
patent: 57087869 (1982-06-01), None
patent: WO 02051949 (2002-04-01), None
patent: WO2004099323 (2004-11-01), None
“Paint and Coating Additives” 2 pages, internet http://www.lubrizol.com/Coating/specialty/default.asp, retrieved Mar. 8, 2004.*
“Reference Information FDA Complaint Coating Using Lubrizol® 2063” 1 page, internet http://www.lubrizol.com/CoatingsReference/lz2063FDA.asp, retrieved Mar. 8, 2004.*
“Lubrizol® 2063” 1 page, internet http://www.lubrizol.com/CoatingProduct/lz2063.asp, retrieved Mar. 8, 2004.*
“Borchi® Gen HMP” 2 pages, internet linked from http://www.borchers.de/index.cfm?PAGE_ID=197, retrieved Mar. 8, 2004.*
Derwent abstract ACC-NO: 1982-56292E for JP 57087869-A.*
International Search Report PCT/US2004/013108, International Filing Date Apr. 27, 2004.

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