Coating a substrate with an ionomer

Coating processes – With post-treatment of coating or coating material – Heating or drying

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Details

427212, 4272133, 71 6407, 71 6411, B05D 302

Patent

active

051907976

ABSTRACT:
The present invention relates to a process for the encapsulation of a solid substrate with a neutralized sulfonated polymer, which comprises the steps of: (a) forming a solution of a non-conjugated, diene polymer in a solvent selected from the group consisting of aliphatic, aromatic hydrocarbons and mixtures thereof; (b) contacting the solution of the unsaturated polymer with a sulfonating agent at a sufficient temperature and for a sufficient period of time to form a solution of a sulfonated polymer containing free acid; (c) forming a solution of a base selected from the group consisting of alkali metal hydroxides and mixtures thereof in a mixtrue of an aliphatic alcohol and a hydrocarbon, the hydrocarbon being selected from the group consisting of aliphatic and aromatic hydrocarbons and mixtures thereof; (d) adding the solution of base to the solution of sulfonated polymer in an amount sufficient to neutralize the polymer and the free acid, thereby forming a coating solution; (e) contacting the solid substrate with the coating solution while removing the solvent therefrom, thereby forming an encapsulated substrate. In a preferred embodiment, the solvent removed during step (e) is recovered and distilled to separate the solvent into at least two fractions, a fraction containing substantially hydrocarbon and an alcohol containing fraction. The separated solvents are then recycled to dissolve the polymer in step (a) and to dissolve the base in step (c).

REFERENCES:
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patent: 4741956 (1988-05-01), Thaler et al.
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patent: 4979980 (1990-12-01), Thaler et al.
patent: 4988377 (1919-01-01), Manalastas et al.
patent: 5006147 (1991-04-01), Thaler et al.

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