Coated sunglass lens

Optics: eye examining – vision testing and correcting – Spectacles and eyeglasses – Ophthalmic lenses or blanks

Reexamination Certificate

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C351S051000, C351S177000, C359S360000, C359S585000

Reexamination Certificate

active

06793339

ABSTRACT:

The present invention relates to optical articles bearing a light absorbing coating.
The optical articles according to the present invention are preferably employed in the preparation of articles such as optical lenses, including spectacle lenses, including sunglass lenses, visors, shields, glass sheets, protective screens, and the like.
Sunglasses generally serve to attenuate transmitted light, but aside from the level of light transmittance, there are other features that distinguish different sunglass lenses, such as material, transmitted colour, scratch resistance, reduction of side glare, ultra-violet transmittance, cosmetic appearance etc. Coatings may be applied to enhance the performance of sunglass lenses. Such coatings might include scratch resistant coatings, hydrophobic coatings for easier cleaning, anti-reflection coatings on the concave surface for reducing side glare or “mirror” (or “interference”) coatings for producing fashionable lens colours. General purpose sunglass lenses should meet certain standard specifications, including luminous transmittance, traffic signal recognition and UV transmittance (e.g. ANSI Z80.1-1995).
In addition to their performance characteristics, sunglass lenses should be simple and economical to produce in a reliable manner.
As is known in the prior art, the preferred method for producing sunglass lenses is dependent on the material involved. In all cases a light-attenuating material is either incorporated into the substrate material or applied over its surface in a process known as “tinting”. For example, glass lenses are often tinted by introducing coloured additives to the molten glass, and similarly polycarbonate lenses are injection-moulded from pre-coloured plastic granules. A disadvantage associated with this method of production is that for economical reasons, very large batches of coloured raw material must be purchased, limiting flexibility in the range of tint colours that can be offered in the sunglass lens product. Moreover, prescription sunglass lenses with highly varying thickness will also exhibit non-uniform transmittance when coloured in this way. Hard resin lenses (another commonly used ophthalmic plastic) are usually dipped in a hot, liquid dye which is imbibed into the plastic. This process also has disadvantages, such as difficulty in achieving tint uniformity, poor colour reproducibility and its requirement that if the lens has a scratch resistant coating, it must be semi-permeable to allow imbibation of the dye molecules, hence compromising the scratch resistance. If a reflective mirror coating is desired, the tinted substrate is then cleaned and coated in an evaporative box coater. Such multi-stage processes are both time-consuming and expensive.
One proposal in the prior art to overcome some of the problems associated with lens tinting is to apply the light absorbing material as a thin film on an essentially transparent substrate. U.S. Pat. No. 5,770,259 (Parker and Soane) describes a method for tinting sunglass lenses using a curable primer containing a tinting agent. Vacuum deposition allows the light absorbing coating to be applied in a relatively fast, clean, flexible and controllable manner. U.S. Pat. No. 5,729,323 (Arden and Cumbo) describes a sunglass formed by depositing a multi-layer light absorbing coating containing TiO
x
(x=0.2-1.5) on the concave surface of the substrate. The coating is anti-reflective from the wearer's side of the lens. U.S. Pat. No. 3,679,291 (Apfel and Gelber) describes a metal-dielectric multi-layer coating that is light absorbing and has an asymmetric reflectance, being anti-reflective from one side and with strong colour on the other side.
Another time-consuming step in the production of corrective sunglass lenses is the surfacing of the lenses. Corrective (or prescription) sunglass lenses are often dispensed using “semi-finished blanks”—lenses that have a pre-moulded front surface and a back surface that must be ground and polished to satisfy the individual wearer's corrective prescription. For plastic lenses in particular, tinting and the deposition of further lens coatings must be performed after surfacing the lens, resulting in a long and labour-intensive process to produce and deliver the sunglass lenses. One means to simplify and accelerate lens delivery is to employ a wafer lamination scheme, where front and back lens wafers spanning a large range of optical powers are simply glued together to produce a lens of virtually any desired prescription. Instead of maintaining a complex optical grinding and polishing workshop, the optical dispenser need only maintain an inventory of wafers and a lamination unit. The use of fast curing glues allows lenses to be produced in only minutes. Additional performance enhancing coatings may be applied to the wafers at the factory, so that the dispenser may provide the desired product features immediately, simply by selecting the appropriate wafers from his inventory.
For laminated lens wafer systems, for example of the Sola International Matrix®-type, liquid bath tinting is not a desired option—it is a low yield process involving significant handling and possible distortion of fragile wafers. Such tinted lenses may also exhibit poor abrasion and scratch resistance and variable depth of colour.
Moreover, for sunglass lenses in particular, it would be a significant advance in the art if, in addition, reflection of visible light at the concave (or rear) lens surface could be kept sufficiently low to avoid glare from incident light at the concave surface.
Accordingly, it is an object of the present invention to overcome, or at least alleviate, one or more of the difficulties or deficiencies related to the prior art.
Accordingly, in a first aspect of the present invention there is provided an optical lens including
an optically clear lens element; and
a light absorbing coating on the front surface of the lens that
attenuates transmitted light;
has a coloured or colourless reflection as seen from the front of the sunglass lens; and
is anti-reflective as seen from the eye side of the lens.
It will be understood that, in accordance with the present invention, one or more surfaces of an optical lens is coated with a light absorbing coating. This light absorbing coating may be applied to either the outside surface of the lens or an inside surface of a lens wafer (where it is protected from scratching once the wafers are laminated) as discussed below. The light absorbing coating may preferably serve three purposes at once—to attenuate transmitted light, effectively providing the sunglass “tint,” to produce a reflected colour that is of pleasing appearance and to reduce or minimise back reflections seen by a wearer of the sunglass lenses.
In a preferred form, the light absorbing coating may function as a mirror coating. Thus, the tinting and mirror coating processes may be combined into one with this coating.
Further the deposited coating may exhibit much improved adhesion and thus improved abrasion resistance.
In a further aspect of the present invention there is provided an optical lens including
an optically clear lens element; and
a light absorbing coating on the rear surface of the lens, such that the light absorbing coating
attenuates transmitted light;
has a coloured or colourless reflection as seen from the front of the sunglass lens; and
is anti-reflective as seen from the eye side of the lens.
Preferably the light absorbing coating is an asymmetric reflectance, light absorbing coating including a plurality of overlapping light absorbing and generally transparent layers, and wherein the thickness and/or number of the respective layers are selected to provide an anti-reflective effect on the eye side of the optical lens and a desired colour on the other side of the lens.
By the term “coloured or colourless reflection”, as used herein, we mean, that light from a white fluorescent source is reflected from the surface of the optical lens to an observer such that the reflected light is coloured or white respectively.
By th

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