Optical waveguides – Optical fiber waveguide with cladding – Utilizing multiple core or cladding
Reexamination Certificate
2000-04-17
2001-09-11
Healy, Brian (Department: 2874)
Optical waveguides
Optical fiber waveguide with cladding
Utilizing multiple core or cladding
C385S123000, C385S127000, C385S141000, C385S114000, C427S163200, C065S385000
Reexamination Certificate
active
06289158
ABSTRACT:
TECHNICAL FIELD
This invention relates generally to protective coatings for optical fiber, and more particularly to coatings which omit adhesion promoters but nonetheless provide enhanced delamination resistance at typical ambient temperatures and reduced delamination resistance at elevated temperatures typically used in field stripping.
BACKGROUND OF THE INVENTION
In the manufacture of optical fiber, a glass preform rod is suspended vertically and moved into a furnace at a controlled rate. The preform softens in the furnace and a glass fiber (also referred to as an optical fiber) is drawn freely from the molten end of the preform rod by a capstan located at the base of a draw tower. Because the surface of the glass fiber is susceptible to damage caused by abrasion, it is necessary to coat the fiber immediately after it is drawn but before it comes into contact with any surface. Inasmuch as the application of a coating material must not damage the glass surface, the coating material is applied in a liquid state. Once applied, the coating material must solidify before the glass fiber reaches the capstan. This is typically accomplished within a brief time interval by photocuring—a process in which the liquid coating material is converted to a solid upon exposure to electromagnetic radiation, preferably ultraviolet (UV) light.
Because the fibers are thin and flexible, they are readily bent when subjected to mechanical stresses such as those encountered during handling or exposure to varying temperature environments. Such bends in the fiber frequently result in optical loss that is much greater than the intrinsic loss of the fiber itself, and it has been found desirable to protect the glass fiber against such bending. Accordingly, the coating material is required to cushion the glass fiber against bends and two layers of coating materials are typically applied to the drawn optical fiber. An inner (primary) coating, having a relatively low in situ equilibrium modulus, is applied directly to the glass fiber. The in situ modulus of the primary coating is the equilibrium modulus of the coating measured on the fiber. An outer (secondary) coating, having a relatively high modulus, surrounds the primary coating. Together, these coatings protect the inherently high tensile strength of the glass fiber as long as the primary coating remains bonded to the glass.
It is desirable that optical fiber coatings show high delamination resistance at ambient temperatures. The separation of the primary, inner coating from the silica fiber during fiber manufacturing and subsequent handling can result in the formation of a “delamination” area which can adversely affect the optical performance of the fiber. A delaminated area is characterized by a gap at the interface of the fiber and the primary coating. The gap alters the mechanical properties at the point of delamination and may cause fiber transmission losses. Even if the optical performance is substantially not affected, the delamination can result in negative customer perception and is therefore unacceptable.
Delamination resistance at a given temperature is typically determined by supporting the coated fiber under tension on a support member and driving a cylindrical steel member with a known load against the fiber. After impact, the fiber is observed for delamination, and the test is repeated at another position on the fiber. The load for which 50% of the impacted areas delaminate is referred to as the delamination resistance (“DR50”) of the coated fiber. Further details concerning the measurement of delamination resistance are set forth in U.S. Pat. No. 5,908,484 issued to R. L. Decker et al. on Jun. 1, 1999 and entitled “Method of Making A Coated Optical Fiber Comprising Measuring The Delamination Resistance of the Coating”, which is incorporated herein by reference.
In what appears to be a requirement contradictory to delamination resistance, it is also desirable to be able to easily strip the primary coating from the glass fiber at elevated temperatures—particularly when a number of fibers are bonded together in an array such as shown in U.S. Pat. No. 4,900,126. Such an array is frequently referred to as a “ribbon.” Indeed, if the coating materials cannot be cleanly and easily stripped, then splicing and interconnecting operations will be seriously hampered.
It is commonly believed that adhesion promoters form an adhesive bond between the primary coating and the silica fiber that minimizes the tendency to delaminate at ambient temperatures. Examples of commonly used adhesion promoters are: [3-(methacryloyloxy)propyl] trimethoxysilane, g-mercaptopropyltrimethoxysilane, aminopropyl trimethoxysilane, vinyl trimethoxysilane, and allyl trimeythoxysilane, [3-(acryloyloxy)propyl] trimethoxysilane. We believe that all commercially available optical fibers are coated with primary coatings containing adhesion promoters. Typical formulations include adhesion promoters at a loading level of 0.5-3.0 wt. %.
SUMMARY OF THE INVENTION
This invention is predicated upon applicants' discovery that, in reality, adhesion promoters (coupling agents) can reduce the delamination resistance of protective polymer coatings at typical ambient temperatures. Such promoters, chosen to provide covalent bonds with both the fiber and the primary polymer, also increase delamination resistance at typical elevated temperatures used in field stripping.
In accordance with the invention, an optical fiber is provided with a protective primary polymer coating that is substantially free (less than 0.1% by weight and preferably 0%) of adhesion promoters and coupling agents. Advantageously, in lieu of adhesion promoters, the primary polymer coating formulation is provided with an additive which will covalently bond with the fiber but not with the primary polymer.
REFERENCES:
patent: 5181268 (1993-01-01), Chien
patent: 5373577 (1994-12-01), Shackleton et al.
patent: 5373578 (1994-12-01), Parker et al.
patent: 5408564 (1995-04-01), Mills
patent: 5444808 (1995-08-01), Shackleton et al.
patent: 5639846 (1997-06-01), Shustack
Blyler Lee L.
Hale Arturo
Kuck Valerie Jeanne
Paczkowski Mark Anthony
Quan Xina Shu-Wen
Healy Brian
Lowenstein & Sandler PC
Lucent Technologies - Inc.
LandOfFree
Coated optical fiber with enhanced delamination resistance... does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Coated optical fiber with enhanced delamination resistance..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Coated optical fiber with enhanced delamination resistance... will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2510141