Chemistry: electrical and wave energy – Apparatus – Electrolytic
Patent
1980-10-06
1982-05-25
Andrews, R. L.
Chemistry: electrical and wave energy
Apparatus
Electrolytic
427 34, 427226, 427229, 427423, 148 614R, C25B 1108, C25B 1110
Patent
active
043315283
ABSTRACT:
An electrode for use in electrolytic processes comprises a substrate of film-forming metal such as titanium having a porous electrocatalytic coating comprising at least one platinum-group metal and/or oxide thereof possibly mixed with other metal oxides, in an amount of at least about 2 g/m.sup.2 of the platinum-group metal(s) per projected surface area of the substrate. Below the coating is a preformed barrier layer constituted by a surface oxide film grown up from the substrate. This preformed barrier layer has rhodium and/or iridium as metal or compound incorporated in the surface oxide film during formation thereof in an amount of up to 1 g/m.sup.2 (as metal) per projected surface area of the substrate.
REFERENCES:
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patent: 3751295 (1973-08-01), Blumenthal et al.
patent: 3853739 (1974-12-01), Kolb et al.
patent: 3869312 (1975-03-01), Moss et al.
patent: 4203810 (1980-05-01), Warne et al.
Beer Henri B.
Hinden Jean M.
Andrews R. L.
Ban Woodrow W.
Diamond Shamrock Corporation
Hazzard John P.
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