Coated materials and production thereof

Stock material or miscellaneous articles – Composite – Of polycarbonate

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Details

427164, 427165, 4273934, 4273935, 4274072, 4274121, 428442, 428502, 428507, 428911, B32B 2736, B32B 1710, B32B 2742, B05D 302

Patent

active

043328598

ABSTRACT:
Coated formed materials of plastics or glass having improved anti-scratching and anti-fogging properties, are produced by applying to the surface of the formed material an undercoating material comprising (a) a mixture of methylolmelamine in which all or a part of the methylol groups are alkyletherified, and a polyhydric alcohol having a molecular weight of 1,500 or less which may contain an ethylene oxide or propylene oxide chain, or a pre-condensate thereof, (b) a mixture of a monomer having a unit of the formula (I), ##STR1## wherein R.sub.1 and R.sub.2 are independently a hydrogen atom or a lower alkyl, carboxyl or amino group and X is a hydroxyl group-containing side chain, or a homopolymer or copolymer thereof, and a crosslinking agent, or (c) a mixture of (a) and (b), followed by curing it so that the percentage of residual hydroxyl groups therein is from 60 to 90%, thereby forming a resin film (1), and then topcoating the resin film (1) with a topcoating material comprising a mixture of (d) a mixture of methylolmelamine in which all or a part of the methylol groups are alkyletherified, and a polyhydric alcohol having a molecular weight of 100 to 2,000 and an ethylene oxide chain, or a pre-condensate thereof and (e) a surface active agent, followed by curing it so that the percentage of residual hydroxyl groups therein is 35 to 70%, thereby forming a melamine resin film (2).

REFERENCES:
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patent: 3867175 (1975-02-01), Dornte
patent: 3933407 (1976-01-01), Tu et al.
patent: 4052520 (1977-10-01), Chang et al.
patent: 4064308 (1977-12-01), Laurin
patent: 4082894 (1978-04-01), Yoshida
patent: 4127682 (1978-11-01), Laurin
patent: 4164602 (1979-08-01), Fabel
patent: 4177315 (1978-12-01), Ubersax
patent: 4180493 (1979-12-01), Selbeck et al.
patent: 4191804 (1980-03-01), Weber
patent: 4242412 (1980-12-01), Funaki et al.

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