Specialized metallurgical processes – compositions for use therei – Compositions – Consolidated metal powder compositions
Patent
1998-04-23
1999-07-27
Mai, Ngoclan
Specialized metallurgical processes, compositions for use therei
Compositions
Consolidated metal powder compositions
75246, 419 35, 136201, 136240, C22C 1900
Patent
active
059293519
ABSTRACT:
The present invention relates to a thermoelectric material containing CoSb.sub.3 compound for converting heat to electricity, and provides a p-type thermoelectric material of CoSb.sub.3 having a high power factor by achieving high Seebeck coefficient consistently with high electric conductivity in a material of CoSb.sub.3 system without causing increase in heat conductivity. By sintering Co.sub.0.07 Pt.sub.0.03 Sb.sub.3 alloy powder using the spark plasma sintering technique, the material is densified, while growth of grains is restricted, so that a higher electric conductivity is achieved with a heat conductivity maintained in a low level, and the figure of merit as a heat-transfer material is improved. Also, by providing such heat insulating layer as an oxide intermediately in a grain boundary of a compound of CoSb.sub.3 in a sintered body, the heat conductivity is reduced. Further, the Seebeck coefficient is increased by adding a rare earth metal to the thermoelectric material of CoSb.sub.3, and allowing it to be precipitated in grain boundaries of the sintered body.
REFERENCES:
patent: 5610366 (1997-03-01), Fleurial et al.
Gyoten Hisaaki
Kusakabe Hiroki
Takigawa Masuo
Mai Ngoclan
Matsushita Electric - Industrial Co., Ltd.
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