Co-preparartion of 2,7-octadienyl formate, 1,6-octadiene and 4 v

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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585366, 585601, C07C 6704

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active

045543755

ABSTRACT:
A method for preparing 2,7-octadienyl formate by reacting 1,3-butadiene with formic acid in the presence of a platinum(II) catalyst is described. The platinum(II) catalyst is preferably platinum acetylacetonate. A reaction temperature between 50.degree. and 150.degree. C. is preferred, and carbon dioxide and a solvent may also be employed. Tetrahydrofuran and acetone are the preferred aprotic solvents.

REFERENCES:
patent: 3795699 (1974-03-01), Wright
patent: 3872153 (1975-03-01), Wright
patent: 3923875 (1975-12-01), Rose

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