Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1984-03-15
1985-11-19
Shippen, Michael L.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
585366, 585601, C07C 6704
Patent
active
045543755
ABSTRACT:
A method for preparing 2,7-octadienyl formate by reacting 1,3-butadiene with formic acid in the presence of a platinum(II) catalyst is described. The platinum(II) catalyst is preferably platinum acetylacetonate. A reaction temperature between 50.degree. and 150.degree. C. is preferred, and carbon dioxide and a solvent may also be employed. Tetrahydrofuran and acetone are the preferred aprotic solvents.
REFERENCES:
patent: 3795699 (1974-03-01), Wright
patent: 3872153 (1975-03-01), Wright
patent: 3923875 (1975-12-01), Rose
Alexander David C.
Lin Jiang-Jen
Park Jack H.
Priem Kenneth R.
Shippen Michael L.
Texaco Inc.
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