CO Hydrogenation and alcohol homologation by means of soluble gr

Details CO Hydrogenation and alcohol homologation by means of soluble gr CO Hydrogenation and alcohol homologation by means of soluble gr

1981-03-11

1983-12-20

Mars, Howard T.

Chemistry: fischer-tropsch processes; or purification or recover

Liquid phase fischer-tropsch reaction

C07C 2706

Patent

active

044218621

ABSTRACT:
Hydrogen and carbon monoxide are converted into methanol by means of the catalytic action of soluble ruthenium-carbonyl containing complexes at a temperature of from about 250.degree.-300.degree. C., pressures of from about 54 to 200 MPa and CO/H.sub.2 ratio of from 3:1 to 1:10. The soluble ruthenium-carbonyl containing complex is prepared in situ in the reaction medium from sources of ruthenium capable of forming Ru-CO containing complexes.

REFERENCES:
patent: 2535060 (1950-12-01), Gresham
patent: 2549470 (1951-04-01), Howk et al.
patent: 3833634 (1974-09-01), Pruett et al.
patent: 3957857 (1976-05-01), Pruett et al.
Doyle et al., J. Organomet. Chem., 175 C55-C58, 1979.

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