CO Hydrogenation and alcohol homologation by means of soluble gr

Chemistry: fischer-tropsch processes; or purification or recover – Liquid phase fischer-tropsch reaction

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C07C 2706

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active

044218621

ABSTRACT:
Hydrogen and carbon monoxide are converted into methanol by means of the catalytic action of soluble ruthenium-carbonyl containing complexes at a temperature of from about 250.degree.-300.degree. C., pressures of from about 54 to 200 MPa and CO/H.sub.2 ratio of from 3:1 to 1:10. The soluble ruthenium-carbonyl containing complex is prepared in situ in the reaction medium from sources of ruthenium capable of forming Ru-CO containing complexes.

REFERENCES:
patent: 2535060 (1950-12-01), Gresham
patent: 2549470 (1951-04-01), Howk et al.
patent: 3833634 (1974-09-01), Pruett et al.
patent: 3957857 (1976-05-01), Pruett et al.
Doyle et al., J. Organomet. Chem., 175 C55-C58, 1979.

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