Co/Cr catalyzyed oxidation of cyclohexane

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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562542, C07C 5131, C07C 51215

Patent

active

061472565

ABSTRACT:
Carboxylic acids, e.g., adipic acid, are more selectively prepared by oxidizing cyclohexane with oxygen or an oxygen-containing gas, in liquid phase, in a solvent reaction medium which comprises a polar protic or aprotic solvent, and also in the presence of a catalytically effective amount of catalyst values dissolved in said solvent reaction medium, the catalyst values comprising at least one solvent-soluble cobalt compound and at least one solvent-soluble chromium compound.

REFERENCES:
patent: 3987100 (1976-10-01), Barnette et al.
patent: 4902827 (1990-02-01), Steinmetz et al.

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