Click-reaction crosslinkable multicomponent silicone...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

Reexamination Certificate

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C528S028000, C528S038000

Reexamination Certificate

active

08071708

ABSTRACT:
Multicomponent silicone compositions which can be crosslinked via the click reaction and which, after mixing of the individual components, harden to give an elastomeric material contain:at least one compound (A) or (B),at least one compound (B) or (C), andat least one Cu catalyst (D),where(A) is an organic compound or an organosilicon compound which possesses at least two moieties having terminal aliphatic carbon-carbon triple bonds having terminally bonded hydrogen;(B) is an organic compound or an organosilicon compound which possesses at least two moieties having terminal aliphatic carbon-carbon triple bonds having terminally bonded hydrogen and simultaneously at least two moieties having carbon-bonded azide groups;(C) is an organic compound or an organosilicon compound which possesses at least two moieties having carbon-bonded azide groups.

REFERENCES:
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Rostovtsev, V.V., Green, L.G., Fokin, V.V., Sharpless, K.B., “A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes”, Angew. Chem. Int. Ed. 2002, 41, No. 14, pp. 2569-2599.
Ossipov, D.A., Hilborn, J., “Poly(vinyl alcohol)-Based Hydrogels Formed by ‘Click Chemistry’”, Macromolecules 2006, 39, pp. 1709-1718.
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Binder, W.H., Sachsenhofer, R., “‘Click’ Chemistry in Polymer and Materials Science”, Macromol. Rapid Commun. 2007, 28, pp. 15-54.
Lutz, J.-F., “1,3-Dipolar Cycloadditions of Azides and Alkynes: A Universal Ligation Tool in Polymer and Materials Science”, Angew. Chem. Int. Ed. 2007, 46, pp. 1018-1025.
Wu, P., Feldman, A.K., Nugent, A.K., Hawker, C.J., Scheel, A., Voit, B., Pyun, J., Frechet, J.M.J., Sharpless, K.B., Fokin, V.V., “Efficiency and Fidelity in a Click-Chemistry Route to Triazole Dendrimers by the Copper(I)-Catalyzed Ligation of Azides and Alkynes”, Angew. Chem. Int. Ed. 2004, 43, pp. 3928-3932.
Malkoch, M., Schleicher, K., Drockenmuller, E., Hawker, C.J., Russell, T.P., Wu, P., Fokin, V.V., “Structurally Diverse Dendritic Libraries: A Highly Efficient Functionalization Approach Using Click Chemistry”, Macromolecules 2005, 38, pp. 3663-3678.
Rozkiewicz, D.I., Janczewski, D., Verboom, W., Ravoo, B.J., Reinhoudt, D.N., “‘Click’ Chemistry by Microcontact Printing”, Angew. Chem. Int. Ed. 2006, 45, pp. 5292-5296.
Rohde, R.D., Agnew, H.D., Yeo, W.-S., Bailey, R.C., Heath, J.R., “A Non-Oxidative Approach toward Chemically and Electrochemically Functionalizing Si(111)”, J. Am. Chem. Soc. 2006, 128, pp. 9518-9525.
Diaz, D.D., Punna, S., Holzer, P., McPherson, A.K., Sharpless, K.B., Fokin, V.V., “Click Chemistry in Materials Synthesis. 1. Adhesive Polymers from Copper-Catalyzed Azide-Alkyne Cycloaddition”, J. Polym. Sci: Part A: Polymer Chemistry, vol. 42, 2004, pp. 4392-4403.
Huisgen, R., Szeimies, G., Mobius, L., “Kinetik der Additionen organischer Azide an CC-Mehrfachbindungen”, Chem. Ber. 100, 1967, pp. 2494-2507.
Ranjan, R., Brittain, W.J., “Synthesis of Polyacrylamide-Silica Hybrid Nanoparticle Using Raft Polymerization and Click Chemistry”, Polymer Preprints 2007, 48(1), pp. 797-798.

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