Cleavage of hydroperoxides

Details Cleavage of hydroperoxides Cleavage of hydroperoxides

1983-06-03

1984-12-11

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568311, 568385, 568798, C07C 4553

Patent

active

044879709

ABSTRACT:
Secondary-alkyl substituted benzene hydroperoxides are cleaved to form phenols and ketones by contacting the secondary-alkyl substituted benzene hydroperoxide with a catalyst consisting essentially of about 3:1 to 1:10 by weight of SbF.sub.5 and graphite in the presence of an aromatic or ketone solvent at a temperature of from about 0.degree.-100.degree. C.

REFERENCES:
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patent: 3925495 (1975-12-01), Rodewald
patent: 3959381 (1976-05-01), Arkell et al.
patent: 4116880 (1978-09-01), Olah
patent: 4267380 (1981-05-01), Austin et al.
patent: 4339613 (1982-07-01), Olah
Rodewald, Chem. Abst., vol. 84, #124301c, (1976).

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