Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – For cleaning a specific substrate or removing a specific...
Reexamination Certificate
2000-12-20
2003-09-30
Ogden, N. (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
For cleaning a specific substrate or removing a specific...
C510S159000, C510S424000, C510S490000, C510S477000, C510S505000
Reexamination Certificate
active
06627586
ABSTRACT:
The present invention relates to cleansing compositions. In particular it relates to mild personal cleansing compositions which display improved rinse feel in combination with good skin feel attributes, and foaming properties which are suitable for simultaneously cleansing and conditioning the skin and/or the hair and which may be used, for example, in the form of foam bath preparations, shower products, skin cleansers, hand, face and body cleansers, shampoos, etc.
BACKGROUND OF THE INVENTION
Mild cleansing compositions must satisfy a number of criteria including cleansing power, foaming properties and mildness/low irritancy/good feel with respect to the skin, hair and the ocular mucosae. Skin is made up of several layers of cells which coat and protect the underlying tissue. The keratin and collagen fibrous proteins that form the skeleton of its structure. The outermost of these layers is referred to as the stratum corneum. Hair similarly has a protective outer coating enclosing the hair fibre which is called the cuticle. Anionic surfactants can penetrate the stratum corneum membrane and the cuticle and, by delipidization destroy membrane integrity and loss of barrier and water retention functions. This interference with skin and hair protective membranes can lead to a rough skin feel and eye irritation and may eventually permit the surfactant to trigger immune response creating irritation.
Ideal cosmetic cleansers should cleanse the skin or hair gently, without defatting and/or drying the hair and skin and without irritating the ocular mucosae or leaving skin taut after frequent use. Most lathering soaps, shower and bath products, shampoos and bars fail in this respect.
Certain synthetic surfactants are known to be mild. However, a major drawback of some mild synthetic surfactant systems when formulated for shampooing or personal cleansing is that they have what can be described as a “slippy” or “non-draggy” rinse feel which is not liked by some consumers.
The use of certain surfactants such as potassium laurate, on the other hand, can yield a “draggy” rinse feel but at the expense of clinical skin mildness. Other synthetic surfactants do not provide the soft/smooth skin feel that is desired by consumers.
These facts make the selection of suitable surfactants in the rinse feel and mildness benefit formulation process a delicate balancing act.
Thus a need exists for personal cleansing compositions which deliver a “draggy” rinse feel and/or soft/smooth skin feel while at the same time having excellent skin mildness, in addition to excellent product characteristics such as lather, cleansing, stability, thickening, and rheology.
Surprisingly, it has now been found that personal cleansing compositions having a “draggy” rinse feel and/or soft smooth in use characteristics while at the same time having excellent mildness characteristics are provided by the combination of polymeric esters of polyols with an anionic and/or amphoteric surfactant system.
Polymeric esters of polyols are well known in the field of mechanical lubrication. For example, GB-A-2 134 538, U.S. Pat. No. 3,694,382, JP-A-5 331 482, all of which are incorporated herein by reference, disclose esters of alcohols for use as lubricants; JP-A-5 120 209 discloses the use of polymeric esters of alcohols in compositions for plastic. JP-A-55 085 510, herein incorporated by reference, discloses the use of the polymeric ester of dipentaeiythritol in cosmetic stick and emulsion compositions. JP-A-56 145 209, herein incorporated by reference, discloses the use of the polymeric ester of dipentaerythritol as a lanolin substitute for cosmetics.
Whilst not wishing to be bound by theory, the “draggy” rinse feel is considered to be associated with an increase in wet skin friction. An important mechanism for action of such polymeric esters of polyols is considered to be their ability to deposit and change the surface energy of the skin, i.e. making the skin surface more hydrophobic. During rinsing, the water film is considered to be the lubricant for the skin, and as surface hydrophobicity increases so the water film is destabilised and the surface de-wetted. As a result the water film is at first thinned and then displaced, allowing some direct contact between the surfaces. Both changes increase friction and produce “draggy rinsing”.
SUMMARY OF THE INVENTION
According to the present invention there is provided a personal cleansing composition comprising an anionic and/or amphoteric surfactant and a polymeric ester, the polymeric ester comprising:
(i) a polyol;
(ii) a monocarboxylic acid having from 4 to 30 carbon atoms; and
(iii) a dicarboxylic acid.
The compositions of the present invention provide an improvement in rinse feel while at the same time being exceptionally mild to the skin.
All concentrations and ratios herein are by weight of the cleansing composition, unless otherwise specified. Surfactant chain lengths are also on a weight average chain length basis, unless otherwise specified.
REFERENCES:
patent: 5607980 (1997-03-01), McAtee et al.
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patent: WO 96/37595 (1996-11-01), None
patent: WO 98/24401 (1998-06-01), None
Brooks Alan
Duke Roland Philip
Elliott Russell Phillip
Phipps Nicola Jacqueline
Corstanje Brahm J.
Howell John M.
Ogden N.
Paul Andrew A.
The Procter & Gamble & Company
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