Electricity: measuring and testing – Particle precession resonance – Using a nuclear resonance spectrometer system
Patent
1986-03-03
1987-10-27
Levy, Stewart J.
Electricity: measuring and testing
Particle precession resonance
Using a nuclear resonance spectrometer system
324307, G01R 3320
Patent
active
047032685
ABSTRACT:
A multi-pulse radio frequency signal sequence includes a 90.degree. excitation pulse (50) and at least a first 180.degree. refocusing pulse (52) and a second 180.degree. refocusing pulse (54). The excitation pulse and first refocusing pulse are separated by a duration A and the first and second refocusing pulses are separated by A+B. A free induction decay (60) follows the excitation pulse, a first spin echo (62) occurs a duration A after the first refocusing pulse and a second spin echo (64) occurs the duration B after the second refocusing pulse. A first read gradient (90) is applied between the excitation and first refocusing pulses; a second read gradient (92) is applied between the first refocusing pulse and the first spin echo; a third read gradient (94) is applied between the first spin echo and the second refocusing pulse; and a fourth read gradient (96) is applied between the second refocusing pulse and the second spin echo. Because the 90.degree. and 180.degree. pulses are imperfect, parasitic echoes occur at durations 3A+B, 3A+2B, and 4A+2B after the 90.degree. excitation pulse. To avoid contamination of the spin echo data by the parasitic echoes, the durations A and B are selected such that the parasitic echoes are each displaced from the spin echoes. To shift the parasitic echoes into times which are non-coincident with the spin echoes, the amplitudes of the read gradients are similarly varied between the spin echoes to shift the parasitic echoes relative to the spin echoes.
REFERENCES:
patent: 4297637 (1981-10-01), Crooks et al.
"Spin Echoes" E. L. Hahn, Physical Review, vol. 80, No. 4, Nov. 15, 1950, pp. 580-594.
"Effects of Diffusion on Free Precession in Nuclear Magnetic Resonance Experiments" H. Y. Carr and E. M. Purcell; Physical Review, vol. 94, No. 3, May 1, 1954, pp. 630-638.
"Effects of Diffusion in Nuclear Magnetic Resonance Spin-Echo Experiments", D. E. Woessner Journal of Chemical Physics, vol. 34, No. 6, Jun. 1961, pp. 2057-2061.
"Diffusion and Field Gradient Effects in NMR Fourier Spectroscopy", R. Kaiser, E. Bartholdi, and R. R. Ernst, Journal of Chemical Physics, vol. 60, No. 8, Apr. 1974, pp. 2966-2979.
Gyngell Michael L.
Nayler Graham L.
Levy Stewart J.
O'Shea Kevin D.
Picker International Ltd.
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