Cladophora-form carbon comprising carbon nanomaterials...

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Particulate matter

Reexamination Certificate

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C427S213000, C427S215000, C427S217000

Reexamination Certificate

active

07608331

ABSTRACT:
A fine spherical particle formed of diamond as a core and having carbon nano-materials radially grown therefrom is disclosed, which exhibits the appearance of a Marimo (Cladophora sauteri) particle. Fine diamond catalytic particles2whose surfaces are oxidized and treated to carry a transition metal catalyst are floated and stirred in a gas phase of hydrocarbon while being heated at a selected temperature to bring about a catalytic reaction which synthesizes carbon nano-materials and to grow them on the surface of said oxidized fine diamond particle. Nano fibers or filaments32of a nano size are grown from the fine diamond catalytic particle31as a core to formcladophora-form carbon. The carbon nano-materials if the supported transition metal is Ni or Co become carbon nano-tubes and if it is Pd become coin stacked carbon nano-graphite.

REFERENCES:
patent: 2006/0275219 (2006-12-01), Danjo et al.
patent: 2003-112050 (2003-04-01), None
patent: 2004-277241 (2004-10-01), None
patent: 2004-277925 (2004-10-01), None
Fang et al, “Influence of catalyst oxidation on the growth of nitrogen-containing carbon nanotubes for energy generation and storage applications”, Diamond & Related Materials 16, (2007) 1140-1143.
Nakagawa et al, “Diamond-supported metal catalyst: a novel medium for hydrogen production from methanol decomposition”, Catalysis Letters, vol. 80, No. 3-4, Jun. 2002, pp. 161-164.
Wikipedia.com, “Marimo”, 2009; weblink: http://en.wikipedia.org/wiki/Marimo.
Statemaster.com, Cladophora, 2009, weblink: http://www.statemaster.com/encyclopedia/cladophora.
Marimo-web.org, Marimo, 2009; weblink: http://marimo-web.org/en/index/html.
Translation of International Preliminary Report on Patentability mailed Jan. 18, 2007 of International Application No. PCT/JP2005/008833.
International Search Report of PCT/JP2005/008833, date of mailing Aug. 16, 2005.

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