Citrate/ethylenediamine gel method for forming high temperature

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

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505735, 505737, 252518, 252521, H01L 3912, H01B 108

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active

050666363

ABSTRACT:
A citrate/ethylenediamine gel method for forming oxide superconductors of the Y-Ba-Cu-O, Bi-Ca-Sr-Cu-O, Tl-Ca-Ba-Cu-O system by employing the nitrates of the individual metals and citric acid. Ethylenediamine is then added to form gels. These materials then undergo calcination and sintering processes. The respective superconductors obtained possess a superconducting zero resistance temperature at 93K, 78K and 118K respectively.

REFERENCES:
Liu et al., "Application of Gel Technology in Preparation of High-Tc Perovskite Superconductors", Mat. Res. Soc. Symp. Proc. vol. 99, Apr. 1988.
Wang et al., "Comparison of Carbonate, Citrate, and Oxalate Chemical Routes to the High-Tc . . . ," Inorg. Chem. vol. 26, 1474-1476 (1987).
Mahloojchi et al., "Production and Sintering of Oxide Superconductor via the Citrate Gel Process," Brit. Cer. Proc. vol. 40, 1-14 (1988).

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