Cis-6-undecene-1-chloride and a method for the preparation there

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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570217, 570219, C07C 1726, C07C 2104

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active

043318207

ABSTRACT:
A novel compound cis-6-undecene-1-chloride is prepared by reacting cis-3-octene-1-chloride with metallic magnesium to give a Grignard reagent of the chloride and then reacting the Grignard reagent with 1-bromo-3-chloropropane in the presence of a lithium copper chloride as a catalyst. The inventive compound is a useful intermediate compound for the synthetic preparation of several kinds of so-called sexual pheromone compounds of noxious insects. As an example of such sexual pheromone compounds, the synthetic preparation of cis-9-tetradecenyl acetate is described.

REFERENCES:
patent: 3459819 (1969-08-01), Suzuki
patent: 4292454 (1981-09-01), Cardenas et al.
Jacobson, Insect Sex Pheromones, 1972, p. 229.

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