Chromatography apparatus with electrochemical detector having ca

Chemical apparatus and process disinfecting – deodorizing – preser – Analyzer – structured indicator – or manipulative laboratory... – Means for analyzing liquid or solid sample

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73 611C, 204 1T, 204195R, 204294, G01N 3108

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active

043437672

ABSTRACT:
A flow-through electrochemical cell distinguished by the feature of a working electrode comprising selected carbon black powder(s) dispersed within an inert binder. An outstanding characteristic of the invention is the markedly improved signal
oise ratio of the electrode which enables a significant gain in the sensitivity level at which trace compounds can be detected. As an example of utility, as little as 5 to 30 parts per billion (ppb) of most phenolic compounds in water can be determined by liquid chromatographic separation of species and amperometric electrochemical detection, using the described flow-through cell to monitor the column effluent. No sample preparation is required.

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Gaylor, V. F. et al., Anal. Chem., vol. 29, pp. 224-228, Feb. 1957.
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Pungor, E. et al., Z. Folyoirat, vol. 77, pp. 294-298, (1971).
Kissinger, P. T. et al., Anal. Letters, vol. 6, pp. 465-477, (1973).

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