Gas separation: apparatus – Chromatography type apparatus
Patent
1995-06-26
1997-06-10
Spitzer, Robert
Gas separation: apparatus
Chromatography type apparatus
96108, 96154, 55524, B01D 1508, B01D 5304
Patent
active
056371357
ABSTRACT:
Chromatographically active stationary phases and adsorbents are made from sol-gels produced by the hydrolysis and condensation of alkoxysilanes that contain hydrolyzable alkoxy groups and non-hydrolyzable organo groups. The organo groups provide chromatographic activity in the resulting hybrid organic-inorganic material. Deposited as hybrid sol-gel coatings on solid supports, the coatings are heated to activate them. Hybrid organic-inorganic materials which contain different organic groups distributed in an inorganic network may be designed for the improved analysis of specific groups of compounds by the selection of the organo groups. Hydrocarbon mixtures may be advantageously analyzed by such hybrid materials.
REFERENCES:
patent: 2676182 (1954-04-01), Dandt et al.
patent: 3500616 (1970-03-01), Bossart
patent: 3722181 (1973-03-01), Kirkland et al.
patent: 3922392 (1975-11-01), Kohlschutter et al.
patent: 4043905 (1977-08-01), Novotny et al.
patent: 4145506 (1979-03-01), Yamamoto et al.
patent: 4177315 (1979-12-01), Ubersax
patent: 4199330 (1980-04-01), Nestrick et al.
patent: 4242227 (1980-12-01), Nestrick et al.
patent: 4290893 (1981-09-01), Hare et al.
patent: 4293415 (1981-10-01), Bente et al.
patent: 4303529 (1981-12-01), Huckins et al.
patent: 4389385 (1983-06-01), Ramsay
patent: 4490278 (1984-12-01), Schubert et al.
patent: 4640909 (1987-02-01), Ramsden et al.
patent: 4650784 (1987-03-01), Ramsden et al.
patent: 4902413 (1990-02-01), Stout et al.
patent: 4927539 (1990-05-01), Stevens et al.
patent: 5066395 (1991-11-01), Ramsden et al.
patent: 5110784 (1992-05-01), Williams et al.
patent: 5137627 (1992-08-01), Feibush
patent: 5176832 (1993-01-01), Dorta et al.
patent: 5178756 (1993-01-01), Jarrett et al.
patent: 5224972 (1993-07-01), Frye et al.
Crego et al, Preparation of Open Tubular Columns for Reversed-Phase High Performance Liquid, Chromatography, Anal. Chem., 1993, 65, 1615-1621.
Schmidt, Chemistry of Material Preparation By The Sol-Gel Process, Journal of Non-Crystalline Solids, 100 (1988) 51-64.
Schmidt, New Type of Non-Crystalline Solids Between Inorganic and Organic Materials, J. of Non-Crystalline Solids, 73 (1985) 681-691.
Cowper et al, The Analysis of Gases by Chromatography, Pergamon Press (1983), 47-48.
Greene et al, Use of Silica Gel and Alumina in Gas-Adsorption Chromatography, Anal. Chem., 29, 1055 (1957).
Thornberry, Isothermal Gas Chromatographic Separation of Carbon Dioxide, Carbon Oxysulfide, Hydrogen Sulfide, Carbon Disulfide, and Sulfur Dioxide, Analytical Chemistry, vol. 43, No. 3, Mar. 1971, 452-453.
Guthrie et al, Overview of Phase Development in Capillary Gas Chromatography, LC-GC, vol. 12, No. 2, Feb. 1994.
Trash, Methylsilicones-Their Chemistry and Use as Gas Chromatographic Liquid Phases, J. Chromatographic Science, Apr. 1973, 196-198.
Coleman, Chemistry of Liquid Phases-Other Silicones J. Chromatographic Science, vol. 11, apr. 1973, 198-201.
Cowper et al, The Analysis of Gases by Gas Chromatography, Pergamon Press, (1985), Chapter 3, 38-52.
Babonneau et al, Structural Characterization of Gels Prepared from Co-Hydrolysis of Tetraethoxy Silane and Dimethyldiethoxysilane, J. Non-Crystalline Solids, 147-148, pp. 280-284, 1992.
Babonneau et al, Dimethyldiethoxysilane/Tetraethoxysilane Copolymers, Chemistry of Materials, vol. 1, No. 5, 1989, 554-558.
Huang et al, Structure-Property Behavior of New Hybrid Materials Incorporating Oligomeric Species into Sol-Gel Glasses, Macro-Molecules, vol. 20, No. 6, 1987, 1322-1330.
Mackenzie et al, Rubbery Ormosils and their Applications, J. of Non-Crystalline Solids 147 & 148 (1992) 271-279.
Leu et al, Organically Modified Sol-Gel Sensors, Analytical Chemistry, vol. 67, No. 1, Jan. 1, 1995, 22A-30A.
Guizard et al, Hybrid Organic-Inorganic Materials Applied to Membrane Preparation, New J. Chem., 1994, 18, 1097-1107.
Sydor et al, Comparison of Porous Copolymers and Related Adsorbents for the Stripping of Low Molecular Weight Compounds from a Flowing Air Stream, Anal. Chem. 1978, 50; 1842-1847.
Guo et al, A Stationary Phase for Open Tubular Liquid Chromatography and Electrochromatography Using Sol-Gel Technology, Anal. Chem. 1995, 67, 2511-2516.
Ottenstein Daniel M.
Pantano Carlo G.
Capillary Technology Corporation
Mich, Jr. Alex
Spitzer Robert
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