Chromatographic separation

Liquid purification or separation – With alarm – indicator – register – recorder – signal or... – Responsive to fluid flow

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210198C, B01D 1508

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active

040160742

ABSTRACT:
In the liquid chromatographic analysis of a sample containing two or more constituents which are chromatograhically separable using an aqueous ether carrier liquid, an effective amount of water is added to the chromatographic carrier liquid thereby increasing the efficiency of the chromatographic separation and decreasing the incidence of chromatographic column plugging. In a preferred embodiment, addition of a small amount of water to a tetrahydrofuran carrier liquid results in substantial improvement in the analysis of a sulfuric acid alkylation catalyst wherein a sample containing sulfuric acid and other chromatographically separatable organic materials is separated in order to measure the relative proportions of sulfuric acid and hydrocarbon or other materials within the sample.

REFERENCES:
patent: 2287732 (1942-06-01), Frey
patent: 2430673 (1947-11-01), Gibson et al.
patent: 3246047 (1966-04-01), Chapman et al.
patent: 3352643 (1967-11-01), Ando et al.
patent: 3522725 (1970-08-01), Waters
patent: 3846297 (1974-11-01), Thaw
Introduction to Modern Liquid Chromatography by Snyder and Kirkland, John Wiley and Sons, New York, N. Y., Rec. Scientific Library June 23, 1974, pp. 218, 219, 269-271 relied on.
A Rapid Method of Identification and Assessment of Total Crude Oils and Crude Oil Fractions by Gel Permeation Chromatography by J. N. Done and W. K. Reid, Presented before the Div. of Pet. Chem., ACS at Houston, Tex., Feb. 1970.

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