Chromatographic method of separating ruthenium from platinum...

Specialized metallurgical processes – compositions for use therei – Processes – Free metal or alloy reductant contains magnesium

Reexamination Certificate

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Reexamination Certificate

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10415705

ABSTRACT:
A chromatographic separation method separates ruthenium from other platinum group metals in a feed solution, by converting the Ru to a nitrosyl complex, retaining the nitrosyl complex temporarily on the chromatography column and subsequently eluting Ru, for example using an oxidising or reducing eluent. FIG.1shows the elution profile obtained from a mixture of Rh chloro-complexes (Peak 1) and Ru nitrosyl species (Peak 2).

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Frank Bottomley, “Nitrosyl Complexes of Ruthenium,”Coordination Chemistry Reviews,vol. 26, No. 1, Jun. 1978, pp. 7-32.
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International Search Report from International Appl. No. PCT/GB01/04745, dated Jan. 31, 2002.
British Search Report from British Application No. 0026809.4 dated May 24, 2001.

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